固化单宁树脂分离富集-原子吸收法测定痕量贵金属的分析-analysis of determination of trace precious metals by separation and enrichment of solidified tannin resin - atomic absorption spectrometry.docxVIP

IIIIAbstractWith the development of science and technology, sensitive, rapid, reproducible, simple and accurate analytical methods are required for the determination of trace elements in geological, biological and environmental samples. The direct determination of extremely low concentration of precious metal element with modern atomic spectroscopic method, such as flame atomic absorption spectrometry (FAAS) is so difficult. On the one hand the components to be determined in samples is lower than the sensitivity of these techniques. On the other hand, the complicated sample composition and the existence of matrix interference are the reason why the separation and preconcentration of trace elements in samples is often required to improve the sensitivity and the selectivity.A new macroporous adsorption resin immobilized tannins was prepared by immobilizing tannins on styrene-divinylbenzene copolymer using Mannich reaction, based on reading numerous references and reviewing the present researches of adsorption resin and the functional polymers of tannin acid. The separation and concentration behavior of Au3+, Pd2+, Ag+ ions had been studied respectively, and then new methods for analysis and determination by FAAS of trace noble metal ions have been established. The methods were simple / accurateand highly selection. The major contents include four parts, there are described as follows:The research and applying of separation, concentration noble metals with the means of chemistry in atomic adsorption spectrometry detemination were reviewed in analysis of trace noble metals. The structure and characteristics of tannins and its ability of complexation were introduced in detail. At the same time, the synthetic method of functional polymer HYPERLINK /material/ material and the research progress was summarized.A new macroporous adsorption resin immobilized tannins was prepared by immobilizing tannins on macroporous adsorption resin using Mannich reaction. Then the product w