水杨醛衍生物的合成 表征及其光物理性质的分析-synthesis and characterization of salicylaldehyde derivatives and analysis of their photophysical properties.docxVIP

II II 湘潭大学硕士学位论文 题目：水杨醛衍生物的合成、表征及其光谱性能的研究 的荧光强度受溶剂影响，在甲醇溶剂中相对于在二氯甲烷和甲苯溶剂中具有更强 的荧光，荧光衰减在甲苯溶剂中主要遵循单指数衰减，在甲醇和二氯甲烷溶剂中 能观察到双指数衰减，这说明在这些溶剂中存在两种活性物种。 关键词：水杨醛；紫外；荧光；瞬态吸收。 Abstract In this paper, a series of Schiff-base ligands, benzimidazole ligands and corresponding Zn(II) complexes based on salicylaldehyde were prepared and characterized, and their photophysical properties in different solvents were investigated. According to experiments, we have found that the fluorescence intensity was greatly enhanced when coordination with zinc(II) and/or in protic solvent such as methanol. The geometrical rigidity of the molecule significantly affected the fluorescence intensity, and all compound showed large Stokes shifted due to excited-state intramolecular proton transfer (ESIPT). Five parts are included in this paper as follows: Part I: In this section, I was mainly discussed the origin, occurrence mechanism, application, and prospect of the fluorescence, and introduced the research purpose and significance of the subject. Part II: A series of 2-benzhydryl-4-methyl-6-((phenylimino)methyl)-phenol ligands were synthesized and characterized by NMR, IR, and elementary analysis. And 2-benzhydryl-6-((mesitylimino)methyl)-4-methylphenol (L4) was futher confirmed by single-crystal X-ray diffraction. In addition, the photophysical properties of all ligands (L1-L5) were studied in different polarity solvent (such as methanol, THF, dichloromethane and toluene), we have found that all ligands showed very weak fluorescence intensity due to excited state intramolecular proton transfer (ESIPT), and all ligands exhibited large Stokes shift. Part III: A series of quadridentate (N^O) zinc(II) complexes were synthesized, all complexes were characterized by IR and elementary analysis, complexes C2 and C5 were further confirmed by single-crystal X-ray diffraction. In addition, the UV-vis absorption and fluorescence spectral properties of ligands and their Zn(II) complexes were investigated. According