双亲性纳米ti02复合粒子改性聚偏氟乙烯超滤膜的分析-analysis of polyvinylidene fluoride ultrafiltration membrane modified by amphiphilic nano - ti02 composite particles.docxVIP

ABSTRACTAsexcellentperformance,polyvinylidenefluoride(PVDF)hasbecomeamajormicrofiltrationandultrafiltrationmembranematerials.ButtheapplicationofPVDFmembraneinthewatertreatmentwaslimitedbecausePVDFmembraneishydrophobicandeasilycompacted.Accordingtotheprincipleofmoleculardesign,theamphiphilicnano-TiO2compositeparticleswasdesignedandsynthesized,whichhasimprovedthehydrophilicityandcompactibilityofPVDFultrafiltrationmembrane,usingthemtomodifyPVDFultrafiltrationmembrane,topreparePVDFultrafiltrationmembraneofhighwaterflux,resistanttopollutionandgoodcompaction.Accordingtotheprincipleofmoleculardesign,theamphiphilicacrylicacidcopolymer-silanecouplingagentKH570-nano-TiO2compositeparticlesisdesignedandsynthesized,thesynthesisprocessofthecompositeparticlesareasfollows:theamountofKH570is10wt.%,couplingagentgraftratioisthehighest,reached7.62%,thedispersionofnano-TiO2significantlyimproved;whentheinitiatordosageis0.2%,monomercontentis10g,thepolymerizationtemperatureis75℃,polymerizationtimeis3h,polymergraftratioisthehighest,reached61.3%.PVDFfilm-formingprocesswillaffectmembranestructureandperformance,throughexperimentresults,whenPVDFconcentrationis16wt.%,additiveis4wt.%PVP,solventisDMAc,bathconcentrationis10%ethanol,temperatureis20℃,theperformanceofthemembraneisbetter.Addingamphiphilicnano-TiO2compositeparticles,waterfluehasincreasedfrom80.8L/(m2h)ofpuremembraneto223.3L/(m2h)ofmodifiedmembrane,watercontactanglehasdeclinedfrom85.6°to47.1°,compactioncoefficientshasincreasedfrom-0.50to-0.04,thewaterflue,hydrophilic,compactionofthemembranehavesignificantlyimproved.ThemethodofimmersionprecipitationphaseinversionisusedtopreparePVDFmembrane.Whenthecompositionofthesystemchangesfromabovethecriticalpointofthecompositionintothemetastablephaseregion,thesystemwilloccurpoornucleationliquid-liquidphase,otherwise,itwilloccurrichnucleationliquid-liquidphase.Thispaperhasproposedatheoreticalmodelintheprocessofamphiphilicnano-TiO2compositeparticlesmodifyPVDFultrafiltrationmembrane,hydrophobicallymodifi