四种n-羟基-9,10-蒽醌-2,3-二酰亚胺化合物的合成研究-synthesis of four n - hydroxy - 9,10 - anthraquinone - 2,3 - diimide compounds.docxVIP

AbstractOxidationofhydrocarbonsplaysanimportantroleinchemicalproduction.Theresearchofnovelcatalystshasbeenachallengingsubject.NHPI,asasmallmoleculecatalyst,cancatalyzethereactionofmolecularoxygenwithaseriesofhydrocarbonsefficientlyunderthemildconditions,andbecomethefocusforacademicresearchteams.Thestudyfoundthat,catalystactivitycanbegreatlyimprovedwhenthevariousco-catalystadded.Anthraquinone(AQ),asanidealcocatalystinthecatalyticsystemofNHPIandnonmetalcocatalyst.Buttherecoveryofthecatalystisstillhardtoovercomeinthistwo-componentsystem.Inthepresentwork,severalmoleculescontainingthestructureofanthraquinoneandNHPI,havebeendesigned,synthesizedandappliedasone-componentsysteminaerobicoxidation.Inthispaper,wedesignedandsynthesizedfourcatalystsincludingN-hydroxy-5,6,7,8-tetrachloro-9,10-anthraquinone-2,3-dicarboximide,(referredNHTCADI),N-hydroxy-5,8-dichloro-9,10-anthraquinone-2,3-dicarboximide,(referredNHDCADI),N-hydroxy-5-hydroxy-8-chloro-9,10-anthraquinone-2,3-dicarboximide,(referredNH-HCADI)andN-hydroxy-5,8-dihydroxy-9,10-anthraquinone-2,3-dicarboximide,refer-redNHDHADI).Thesemoleculesweresynthesizedfrom1,2,3,4-tetrachlorobenzene,p-dichloro-benzene,4-chlorophenolandhydroquinoneviamultistepreactionsequences:Friedel-Craftsacylation,cyclization,chlorinationandN-hydroxy.NMRdetermineditsstructure,andthetotalyieldwas17%(NHTCADI),16%(NHDCADI),12%(NHHCADI),2%(NHDHADI).Wehavestudiedtheactivityofthreenovelcatalystsinethylbenzeneoxidationreaction.Substratewasreactedinthepresenceofcatalyst(2mol%)inacetonitrileunderadioxygenatmosphere(0.4MPa)at110℃for10h.Theconversionofethylbenzenewas19%(NHTCADI),22%(NHDCADI)and20%(NHHCADI).Keywords:N-hydroxy-9,10-anthraquinone-2,3-dicarboximide,Synthesis,N-oxylradical,AerobicoxidationofhydrocarbonsII目录摘要............................................................................................................IAbstract......................................................................................................II目录...........................