四种邻苯二甲酸酯在黄河兰州段水体中环境行为的分析-analysis of environmental behaviors of four phthalates in lanzhou section of yellow river.docxVIP

ABSTRACTDimethylphthalate(DMP),Diethylphthalate(DEP),Di-n-propylphthalate(DnPrP)andDibutylphthalate(DBP),listedasEndocrineDisruptingChemicalbyUSEPAandWWF,wereselectedassubjectsinthispaper,andthedistributioncharactersandthepollutionsituationoftheminyellowriverofLanzhousectionwerestudiedsystemicallyforthefirsttime.EnvironmentalbehaviorsofDMP、DEP、DnPrPandDBPweresimulatedinourlaboratoryexperimentsaswell.Adsorptioncharactersincludingadsorptionthermodynamics,adsorptionkineticsandtheeffectsofconditionsonthemwereemphasizedon.Thepresentworkaimstorevealthemigration,transportandtransformationofphthalicacidesters(PAEs)inwatersoftheYellowRiver,andtoestablishatheoreticbasisfortheprojectionandtreatmentsofthewatersinYellowRiver.Thispaperconsistsofthreeparts.Section1.AreviewChapter1.AreviewontheEnvironmentalbehaviorsofphthalicacidestersanditsdevelopmentInthischapter,thephysical-chemicalcharacteristicsofPAEsandindustrialapplicationsandsourcesofthemwereintroduced,andtheireffectsonecologyenvironmentsbalanceandserioustoxicitywerealsoanalyzedindetail.AnoverviewofthepollutionofPAEsonsediments,waters,andatmosphereswerealsopresented.ThepretreatmenttechniquesandanalysismethodsforPAEsindifferentenvironmentsampleswerereviewedaswell.Section2.TheconcentrationdistributionforthefourphthalicacidestersinwaterenvironmentinYellowriverofLanzhouSectionChapter2.DetectionforthefourphthalicacidestersinthebodyofYellowRiverofLanzhousectionDimethylphthalate(DMP),Diethylphthalate(DEP),Di-n-propylphthalate(DnPrP)andDibutylphthalate(DBP)inwaterphasesamplesfromdifferentsectionofyellowriverofLanzhousectionwereconcentratedbysolidphaseextractiononHLBcartridge,andthecontentsofthemweredetectedwithreverse-phasehighperformanceliquidchromatography.TheresultsshowedthatthetotalconcentrationofthefourPAEsinthewaterphaseoftheYellowRiver（Lanzhousection）intherangeofsectionAandDwere5.041~41.305μg/Linsummerand8.016~29.882μg/Linwinter,respectively.TheobtainedconcentrationsexceededourgovernmentregulationexceptedforDnPrPinwaterphase