石灰石read-f反应器处理含氟废水的研究-study on treatment of fluorine-containing wastewater by limestone read - f reactor.docxVIP

重庆大 重庆大学硕士学位论文 英文摘要 PAGE PAGE IV limestone/READ-F reactor were also discussed. It showed that CaF2 was heterogeneous primary nucleation as advantage nucleation and the electric double layer of limestone induced CaF2 crystallization in limestone reactor. The reaction kinetic equation of CaF2 nprecipitation was rn=3.9771[Ca2+]n [F-] 2-2.4353 and the precipitation generated mainly n in step, kink and hole of limestone. The ion exchange adsorption of F- on READ-F was entropy driven occurring mainly in the external surface and macrospore region. It was fitted to pseudo-second-order reaction kinetics and Frendlich adsorption isotherm equation well. Keywords: Limestone Reactor, READ-F resin, Wastewater containing fluoride, Fluoride removal 重庆大 重庆大学硕士学位论文 目 录 目 录 中文摘要I 英文摘要 II HYPERLINK \l _bookmark0 1 前 言 1 HYPERLINK \l _bookmark1 1.1 课题研究的背景 1 HYPERLINK \l _bookmark2 1.1.1 氟的性质及分布 1 HYPERLINK \l _bookmark3 1.1.2 氟对生态系统的影响 2 HYPERLINK \l _bookmark4 1.1.3 钢铁工业含氟废水的来源 4 HYPERLINK \l _bookmark5 1.2 含氟废水处理研究进展 4 HYPERLINK \l _bookmark6 1.2.1 化学沉淀法 5 HYPERLINK \l _bookmark7 1.2.2 诱导沉淀结晶法 6 HYPERLINK \l _bookmark8 1.2.3 吸附法 6 HYPERLINK \l _bookmark9 1.2.4 混凝沉淀法 8 HYPERLINK \l _bookmark10 1.2.5 膜分离法 9 HYPERLINK \l _bookmark11 1.2.6 电凝聚法 9 HYPERLINK \l _bookmark12 1.2.7 气浮法 10 HYPERLINK \l _bookmark13 1.3 石灰石除氟动力学研究进展 10 HYPERLINK \l _bookmark14 1.3.1 碳酸盐矿物溶解动力学 10 HYPERLINK \l _bookmark15 1.3.2 CaF2 晶体增长动力学 12 HYPERLINK \l _bookmark16 1.4 课题的来源、研究目的及内容 13 HYPERLINK \l _bookmark17 1.4.1 课题来源及意义 13 HYPERLINK \l _bookmark18 1.4.2 研究目的和内容 14 HYPERLINK \l _bookmark19 2 石灰石反应器处理低浓度含氟废水的研究 16 HYPERLINK \l _bookmark20 2.1 石灰石除氟现状 16 HYPERLINK \l _bookmark21 2.2 实验方法及仪器 18 HYPERLINK \l _bookmark22 2.2.1 石灰石反应器的设计 18 HYPERLINK \l _bookmark23 2.2.2 实验材料及仪器 19 HYPERLINK \l _bookmark24 2.2.3 含氟工业废水水质 19 HYPERLINK \l _bookmark25 2.2.4 模拟含氟废水的配制 19 HYPERLINK \l _bookmark26 2.2.5 氟离子浓度的测定 20 HYPERLINK \l _bookmark27 2.3 实验结果与讨论 20