石墨烯基锂硫电池正极材料的制备及性能分析-preparation and performance analysis of graphene-based lithium-sulfur battery anode material.docxVIP

至768.0mAh/g。总体上乙炔黑/石墨烯/硫复合材料的放电比容量明显高于乙炔黑/硫复合材料，循环稳定性也略有一定程度的提高。这也进一步证明石墨烯的掺入有利于材料电化学性能的提高。关键词：锂硫电池复合材料石墨烯乙炔黑电化学性能ABSTRACTLithium-sulfursecondarybatterypossessesabundantadvantages,suchashightheoreticalspecificcapacity,environmentallyfriendlyandlowrawmaterialprice,andthusbeenconsideredasoneofthemostpotentialhighcapacityenergystoragebatterysystems.Whereas,defectslikelowenergyefficiencyandcyclicstabilitycausedbytheelectricinsulatingpropertyofsulfuranditsconsequentdischargeproductaswellasthesolubleintermediateproductexistasbarricadeofitsdevelopment.Inthisarticle,graphemeandgraphemeoxidewereemployedasmajorcarbonmaterial.Grapheneisakindofmaterialwithhighconductivityandmechanicalstrength,largespecificsurfaceareaandstablechemicalproperty.Severalnewkindofcarbonsulfurcompositewassynthesized,includinggraphene-carbonthermalcompositionmaterial,wrappedsulfur,Acetyleneblack(ACblack)/sulfurcompositeandACblack/graphene/sulfurcomposite.XRD,SEM,BET,EDAXandElectrochemicaltestwereemployedtoanalyzethepropertyofdifferentmaterials.graphene/sulfurcompositewassynthesizedbyatwo-stepthermalcompositionmethod,thestack-upstructureofgrapheneiskept,withinwhichsulfurparticlesisuniformlydistributed,noobvioussulfuragglomerationwasdetected.Akindofcore-shellballshapesulfurwrappingmaterialassynthesizedbyatwo-stepreducemethod,withcarbonmaterialoutsidecoveringsulfurparticles.Aselectrochemicaltestshown,underthecurrentdensityof100mAh/g,thegraphene/sulfurthermalcompositionmaterialperformedainitialdischargecapacityof811.5mAh/g,anddecreasedto356.1mah/gafter50cycles;thesulfurwrappingmaterialperformed609.7mAh/gand278.1mAh/grespectivelyaccordingly.Thoughaslightlyincreasingofcapacitywasshownintheinitial4cyclesforsulfurwrappingmaterial,itdecreasedstraightlyafterward,showingalessstablepropertycomparedtothatofgraphene/sulfurcomposite.Astothehalf-wrappedmaterial,therewasabigdecreaseincapacityintheinitialcyclesbutthenthecyclicstabilitypropertywasprettygood.Meanwhile,theall-wrappedmaterialshowedapoorelectrochemicalproper