热处理条件和金属前驱体对co-ppy-tsohc作为氧还原催化剂结构和性能的影响-effects of heat treatment conditions and metal precursors on the structure and properties of co - ppy - t sohc as an oxygen reduction catalyst.docxVIP

EFFECTOFHEAT-TREATMENTCONDITIONSANDMETALPRECURSORSONTHESTRUCTUREANDACTIVITYOFCO-PPY-TSOH/CASOXYGENREDUCTIONCATALYSTSABSTRACTCathodecatalystisoneofthemostimportantfactorsrestrictingthecommercializationofPEMFC,becauseoftheslowkineticsofoxygenreductionreaction,highcostofthenoblemetalcatalystanditslowutilization.Therefore,itisveryimportanttofindakindoflow-costandhigh-efficiencyORRcatalysts.M-N/Ccatalystshavebeenconsideredasthemostlikelyalternativenon-nobleORRcatalysts,whichhavedrawnmoreandmoreattention.AmongvariousM-N/Ccatalysts,Co-PPy-TsOH/Chasbeenprovedtohaveabetteractivitythanothersimilarcatalysts.TheeffectsofpreparationprocessofCo-PPy-TsOH/Ccatalystsincludingheat-treatmentconditions(calcinationtemperaturesandcalcinationhours)andcobaltprecursorsontheelectrocatalyticpropertieshavebeensystematicallystudiedinthispaper,andtheresultshavebeenanalyzedwithphysicochemicaltechniquesofTG,IR,Raman,XRD,TEM,XPS,ICP,EAandEXANES.ItwasfoundthatCo-PPy-TsOH/Ccatalystpreparedwithcobaltacetateasmetalprecursorandcalcinedat800℃for2hoursexhibitedbestORRactivityfollowingfour-electrontransfermechanism.Thecalculatedelectrontransfernumberis3.99andthepeakpotentialforORRis0.71V.XRDpatternshowedthecrystallingphaseinthiscatalystwasprimarilyinformofmetallicCo,exceptafaintCoOcharacteristicpeak;small,uniformdistributedmetalparticleswasfoundinTEMdiagram;XPSspectrumshowedthatmostofthesurfaceNelementsinthiscatalystwaspyrrolicN.IntheobtainedcatalystCo-PPy-TsOH/C,Cactsmainlyascatalystsupport,noC-Nbondcreated,andNcontentisnotthedeterminingfactorofcatalyticORRactivity.IIIKeywords:OxygenReduction,Co-PPy-TsOH/C,Heat-treatment,metalprecursorIV目录摘要........................................................................IIABSTRACT....................................................................III第一章绪论..............................................................-1-1.1引言..................................................................-1-1.2燃料电池综述...........................................................-2-1.2