纳米膨胀石墨银导电胶黏剂的制备及其性能分析-preparation and performance analysis of nano - expanded graphite silver conductive adhesive.docxVIP

ABSTRACTConductiveadhesiveisagelatinoidsubstancewithconductivity,composedofconductivefillerparticlesandresinmatrix,widelyusedinelectronicpacking,integratedcircuit,themanufactureofvarietyofcomponentsandtheassemblyofLCDandmanyotherfields.Inordertodeveloptheidealconductiveadhesive,therelationshipamongparticlesize,morphologyandadhesivepropertieshadtobestudiedsystematically,anditwasinthispaper.Themainresultsareasfollows：First,basedontheintercalationagentreplacementtechnique,optimizedintercalationagent’stypesandexperimentalconditions,andthenaturalflakegraphiteastherawmaterials,abrandnewexpandednano-graphitesheetswiththesizeof3.25±0.87μm(45)oflength，2.18±0.84μm(45)ofwidthand50nmofthinknesswasproduced.Itsgeometricdimensionswassignificantlysmallerthantheclassicexpandedgraphite,andhadthesamechemicalcompositionwithclassicexpandedgraphite.Thisnewexpandednano-graphitesheetslaidthematerialfundationforthefurtherresearchofrelationshipbetweenthefillersizeandconductivityofconductiveadhesive.Second,bythechemicalreductionmethodandhydrothermalsynthesismethod，theglobularsilvernano-particlewiththeparticlesizeof98.9±10.8nm(271),thesilvernano-sheetwiththelengthofthesideof126±36.96nm(189),andthesilvernano-wirewiththediameterof136.2±21.5nm(139)wereobtained,whichprovidedapreparationforthefurtherstudyoftherelationshipbetweenthefillermorphologyandconductivityofconductiveadhesive.Third,thepercolationphenomenonwasfoundwhentheconductiveadhesivewasproducedwithE-44epoxyresinasmatrixandexpandednano-graphitesheetsasconductivefillersintheconditionoffillerscontentreaching15%wt.Thetestresultsshowedthat：Whentheconductivefillersdidnotreachthepercolationthreshold(15%wt),theresistivityoftheconductiveadhesivewasbetweenthesurfaceaeraofnano-graphitesheetsandthesquarerootofthesurfaceaeraofnano-graphitesheets;Whentheconductivefillersexceededthepercolationthreshold(15%wt),theresistivityoftheconductiveadhesiveapproximatedthesquarerootofthesurfaceaeraofnano-graphitesheets.Therefore,onereasonableconclusionwasthatwhent