特殊结构纳米材料的制备与性能研究——梭形ceo2、核壳fe3o4ctio2及中空ctio2-preparation and properties of nano-materials with special structure - spindle ceo 2, core-shell fe 3 o 4c tio 2 and hollow ctio 2.docxVIP

大约为500nm，并且具有明显的空心结构，壳层厚度为70nm。从XRD图中可以看到SiO2的衍射峰消失，表明SiO2被完全除去。同时还研究了葡萄糖添加量对制备的SiO2/C的影响。在实验中发现，随着添加葡萄糖量的增加，产物的壳层厚度也随着增加，但是产物的分散性变差，粒径分布不均一，对比实验结果，选出最佳的葡萄糖添加量为5g。关键词：合成，梭形，核壳，中空，纳米微球PreparationandPropertiesofNanomaterialswithSpecialStructures——spindle-likeCeO2、core-shellFe3O4/C/TiO2andhollowC/TiO2AbstractSynthesisofnanomaterialswithspecialconstructionsisextensivelystudiedinrecentyearsinmaterialsscience.Thepropertiesofmaterialsnotlieonconstitutebutrelatedtoitsmicrostructure.Thenanomaterialswithspecialconstructionshaveuniqueperformanceofoptical、electrical、magneticandcatalyticsuperiortheirbulkcounterparts.Inthisdissertation,synthesisroutesandperformancewithCeO2withspindle-likestructure,Fe3O4/C/TiO2withcore/shellstructureandhollowC/TiO2wereinvestigated.Theprincipalresultsofthedissertationarediscussedasfollows:（1）Single-crystallineCe(OH)CO3withspindle-likestructureswerefabricatedusingonestepprocedurewithoutsurfactantortemplateat120℃for8h.Furthermore,single-crystallineCeO2withspindle-likestructurewasobtainedaftercalcinationofCe(OH)CO3precursor.ThereactiontimeandtheconcentrationofCe(NO3)3·6H2OplayedtheimportantroleduringthegrowthprocessofCe(OH)CO3withspindle-likestructures.Thespindle-likestructureCeO2withthewidthwhichincreasedfromtheendstothecenterwasobtainedwithdurationofreactiontime.AndduringincreasedtheconcentrationofCe(NO3)3·6H2O,theCe(OH)CO3samplewithsphericalandspindle-likestructurewithroughsurfacecoexistinthereactionmixture.ThegrowthmechanismofCe(OH)CO3withspindle-likestructureswerealsodiscussed.Atlast,thecatalyticpropertiesofCeO2weremeasuredinCOoxidation.TheresultshowedthatTheCOconversionratescouldreach66.06%at190℃,andwhenthetemperaturewas220℃,theCOconversionratescouldreach95%,thesingle-crystallinespindle-likeCeO2showedahighcatalyticactivityonCOconversion.（2）MagneticphotocatalystFe3O4/C/TiO2withcore-shellstructurewassuccessfullyfabricatedbyhydrothermal.FromSEMandTEM,Fe3O4/Chadclearcore-shellstructureandthethicknessofCwasabout50nm,thediameterofFe3O4/C/TiO2wasabout3