铁ⅲ—柠檬酸盐体系光降解水中普萘洛尔的分析-analysis of the photodegradation of propranolol in water by iron ⅲ - citrate system.docxVIP

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铁ⅲ—柠檬酸盐体系光降解水中普萘洛尔的分析-analysis of the photodegradation of propranolol in water by iron ⅲ - citrate system.docx

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铁ⅲ—柠檬酸盐体系光降解水中普萘洛尔的分析-analysis of the photodegradation of propranolol in water by iron ⅲ - citrate system

华中科技大学硕士学位论文华中科技大学硕士学位论文 II II 小，反应速率常数 k 显著增加；（2）H2O2 浓度对光降解影响显著，H2O2 浓度的增加有利于 HO?的生成，但过多的 H2O2 会与 HO?反应生成光活性相比 HO?更低的 HO2?；（3）溶液 pH 值对 HO?产量影响显著，最佳 pH=5（4）光照 60 min，TOC 降解率为 80%（5）软件分析得出最佳条件为：[Fe(III)]0/[cit]0/[H2O2]0 = 36.5/358/662 (μM)， pH=5.2，K=0.46 min?1 (t1/2 = 2.17 min) 本研究表明了铁(III)-柠檬酸盐在近中性条件下，对普萘洛尔废水具有高效的降解率，这对实际的普萘洛尔废水的处理具有指导意义。关键词：铁-柠檬酸盐普奈洛尔 H2O2 中心组合实验光降解 PAGE IV PAGE IV Abstract ?-blockers have been used for the treatment of hypertension, angina pectoris, cardiovascular system and lately chronic heart failure since 1962. Among these ?-blockers, propranolol has the highest acute and chronic toxicity. ?-blockers cannot be completely eliminated in sewage treatment plants and they have been widely detected in surface waters. The growing use of ?-blockers has been a relevant issue in environmental research area. Fe(III)-cit complexes have been demonstrated to be excellent Fe(III)-photocatalysts with low toxicity and high photoreactivity,and has been employed for the treatment of organic pollutants. Propranolol can be photodegradated by Fe(III)-cit complexes,so it is very significant for the elimination of propranolol by Fe(III)-cit complexes. Propranolol was chosen in this paper to optimize the process parameters of Fe(III)-cit catalyst and investigate the effect of different Fe(III) species on photoreactivity and the mechanism of the photodegradation. The main objectives and results of this work were presented as follows: The photodegradation of propranolol by Fe(III)-cit complexes: the formation of HO??at different Fe(III)-to-cit molar ratios was analysed. The optimal Fe(III)-to-cit ratio was chosen for the elimination of propranolol by Fe(III)-cit complexes. The effects of 2? ? ? environmental media, including Ca2+, Mg2+, Mn2+, Cu2+, SO4 , HCO3 , NO3 , and humic substances, on the photoreactivity of Fe(III)-cit complexes were first examined. Iron was reused to examine the feasible application of Fe(III)-