铝基超疏水表面沸水法制备工艺与耐蚀性能研究毕设毕业论文.doc

本 科 毕 业 设 计（论文） 题 目：铝基超疏水表面沸水法制备工艺与耐蚀性能研究 学生姓名： 学 号： 专业班级：材料物理 指导教师： 本科毕业设计(论文) 铝基超疏水表面沸水法制备工艺与耐蚀性能研究 摘 要 本文以铝合金为基体材料，通过沸水法处理其表面，并用硬脂酸(十八烷酸)或者硅烷偶联剂进行表面修饰以制备具有超疏水性能的表面。本文研究了铝片粗糙度、沸水处理时间，硬脂酸修饰浓度以及硬脂酸修饰时间等不同工艺对于超疏水表面制备的影响，最后通过电化学试验技术来分析超疏水表面对于铝合金耐蚀性能的影响。结果表明当铝片粗糙度达到1200目、沸水处理时间达到10min、采用浓度为6%的硬脂酸修饰24h能得到超疏水表面，接触角达到了151°。而当用浓度为1%的硅烷偶联剂修饰时，接触角达到了155°。电化学实验结果表明，在模拟海水环境下，经过表面修饰拥有超疏水性能的铝片表面点蚀现象明显减少，材料耐腐蚀性能明显高于原始未处理铝片。 关键词：铝；超疏水表面；沸水法；硬脂酸；正辛基三乙氧基硅烷；电化学实验；  Fabrication of superhydrophobic aluminium alloy surface in boiling water and study on its corrosion resistance Abstract In this paper, the superhydrophobic aluminium alloy surface was prepared by the boiling water treatment and then was fabricated by stearic acid (STA) or silane coupling agent modification. We studied different modified processes’ impact on preparing superhydrophobic surface such as the aluminum roughness, boiling water treatment time, concentration and stearic acid-modified time. Then we analyzed the corrosion resistance of the superhydrophobic surface of aluminum and its alloys by measuring the polarization curves. The results showed that when the roughness of aluminum surface was 1200 mesh, boiling water treatment reaches 10min, modified by 6% concentration of stearic acid by 24h, the superhydrophobic surface contact angle reaches 151°. If the aluminum sheet was modified by 1% concentration of silane coupling agent by 45min, the superhydrophobic surface contact angle reaches 154°. Electrochemical experiments show that the corrosion resistance of aluminum surface with super hydrophobic properties is significantly higher than the original aluminum. Keywords：aluminum; super-hydrophobic surface; boiling water method; stearic acid; noctyltriethoxysilane; polarization curve  目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc422830071 第1章 前言 PAGEREF _Toc422830071 \h 1 HYPERLINK \l _Toc422830072 1.1 铝及铝合金 PAGEREF _Toc422830072 \h 1 HYPERLINK \l _Toc422830073 1.1.1 铝合金的性质与应用 PAGEREF _Toc4228