TiO2光阳极微观结构及其光电池性能材料物理与化学专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - II - Abstract According to the urgent requirment of the green energy, the dye sensitized TiO2 battery was studied. Through adopt different electrode structure, different film making method, different annealing temperature etc, the dependence of parameters on properties of the battery was studied. The results show that when gelatinizing method was used, cracks emerge during evaporation, and systematic research show that it has no relation with evaporation time and sintering temperature. These cracks were erased with more times of dipping, and the more the layers, the better the quality. The ultraviolet-visible absorbtion test show that, the film made with dipping method has a definite absorbtion for the light whose wave length larger than 320 nm, and after adsorbtion of the dye, the absorbtion power for the light increases. The anodes with different number of layers of TiO2 were used to setup the sun energy batteries. The results show that the multy-layer film has higher light- electricity conversion efficiency. This is because the first layer is a block-off layer, which minimized the combination of the I-3 ion at the glass surface. Among the 3 electrods systems, the system in which the glass was the anode, the stainless steel was the opposite pole had the best light-electricity conversion property, since it let most of the rays go through the glass, and the stainless steel has the much lower electric resistance. The light-electricity conversion efficiency decreased as the sintering temperature increased. This is because when the sintering temperature increases, some TiO2 changed their structure from anatase to rutile, the latter has lower light- electricity conversion efficiency. Keywords: solar cess battery, dye sensitize, TiO2, opposite pole - - PAGE IV - 目 录 摘 要 I Abstract II 第 1 章 绪论 1 1.1 课题背景 1 1.1.1 太阳能电池的发展 1 1.1.2 太阳能电池种类 2 1.2 染料敏化太阳能电池 3 1.2.1 染料敏化太阳能电池（DSSC）的结构和基本原理 3 1.2.2 电荷复合的主要途径[8] 4 1.2.3 TiO2 敏化太阳能电池的光电性