TiO2及TiO2-碳质材料复合物的制备及其催化性能的分析-材料物理与化学专业论文.docx

华 华 中 科 技 大 学 博 士 学 位 论 文 IV IV sheets with a dip-coating and liquid phased deposition and the photoelectrocatalytic (PEC) properties of the films were investigated through the degradation of methyl orange. It was demonstrated that CNTs in the TiO2 film significantly decreased the charge transfer resistance and increased the anodic photocurrent response of the film under UV light irradiation. The PEC performance of the CNTs-based composite film could be tuned by controlling the preparation parameters including the deposition time and calcination temperature. The deposition time and calcination temperature were optimized at 1 h and 450 oC, respectively. On the TiO2/CNT film prepared under the optimized conditions, 95% of the initial 10 mg/L methyl orange was degraded within 90 min, which was much higher than the 60% removal seen on the pure TiO2 films. Based on liquid phased depositon, a simple method to synthesize graphene oxide/TiO2 composites as a highly efficient photocatalyst by in situ depositing TiO2 nanoparticles on graphene oxide nano-sheets was developed. There are several advantages for this method. TiO2 nanoparticles are assembled onto the graphene oxide sheet to form larger particle s in the microscale, which could be easily separated by the filtration. Additionally, SEM and BET characterization showed the two-dimensional porous graphene oxide/TiO2 composites had specific surface area of 80 m2 g-1 being considerably larger than that of P25 and the similarly prepared neat TiO2 particles without using graphene oxide. The composites exhibited excellent photocatalytic activity, being influenced by post-calcination temperature, graphene oxide content and solution pH. Under optimal conditions (the concentration of graphite oxide was 75 mg/mL and calcination temperature was 200 oC), the photo-oxidative degradation rate of methyl orange and the photo-reductive conversion rate of Cr(VI) over the composites were as high as 7.4 and 5.4 times that over P25,