TiO2纳米管阵列修饰电极的制备及其在电化学生物传感器中的研究化学专业论文.docxVIP

重庆大学硕士学位论文英文摘要 重庆大学硕士学位论文 英文摘要 PAGE PAGE IV ABSTRACT Titanium dioxide nanotubes (TNT) are a kind of typical one-dimensional nanomaterials, which possess a unique structure and chemical and physical properties. Several recent studies demonstrated that TNTs have a wide range of applications in photoelectricity, catalysis, chemical sensors and biomedical science, and has been becoming a hot spot in the world. Titanium dioxide nanotubes arrays (TNTs) electrode, which was fabricated by anodization and calcination of the titanium substrate, have higher surface areas, well-aligned nanostructures, favorable electron transfer channel, good biocompatibility and good adhesion to the substrate. So, TNTs electrode are promising functional materials for biosensor substrate. In this paper, we fabricated highly-ordered tinatia nanotube arrays as sensor electrode by anodization. Then, to improve electrocatalysis performance of TNTs electrode, nanomaterials were modified on TNTs electrode by electrochemical method for biosensor. The main research contents of this thesis are as follows: ① A novel non-enzymatic glucose biosensor was developed based on the Ni nanoparticles-loaded TiO2 nanotubes arrays (Ni-NPs/TNTs) electrode. The Ni-NPs/TNTs nanocomposites were prepared by pulsed electrodeposition method (PED). The morphology and phase structure of Ni-NPs/TNTs electrode were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The composition of the samples was analyzed by X-ray photoelectron spectroscopy (XPS). SEM image shows that spherical Ni nanoparticles were well dispersed and embedded in the TNTs. XPS demonstrated that the surface of electrode is composed of Nickel and nickel hydroxide. The effect of different prepared-time on the morphology of Ni-NPs/TNTs electrode is investigated. The deposition times were 20, 25 and 30 minutes respectively. With the increase of deposition time, more and more nickel nanoparticles loaded on TNTs can be obser