TiO2纳米线基核壳结构光阳极的制备及应用-材料学专业论文.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract Dye sensitized solar cell (DSSC) has been wildly investigated because of its simple produce, low-cost, materials abundant and environment friendly. Nowadays, photoanode with one-dimensional nano-structure mixed with nanoparticles is proven to be an effective way to improve overall cell performance. Meanwhile, photoanode with core/shell structure which can suppress the recombination and reduce the electrons loss has received considerable attention. In this work, we mainly studied the preparation process of TiO2 nanowires, the composite photoanode of TiO2 nanowirs/nanoparticles and core-shell stucture of TiO2/SrO、TiO2/ZnO for DSSC . TiO2 nanowires are synthesized by hydrothermal treatment and the composite photoanodes are prepared through mixing various mass ratios of nanowires and nanoparticles (PW0, PW10, PW20, and PW100). DSSC with PW10 (nanowires content is 10 wt %) photoanode shows a relative high conversion efficiency of 6.27%. The result shows that the reasonable ratio of nanowires and nanoparticles can promote the electron transfer, reduce the dark current, prolong the electron lifetime, and improve the cell efficiency. The preparation process and cell performance of PW10 photoanode with SrO and ZnO shell coating are studied. The result shows that SrO and ZnO shell coating on TiO2 nano-composites can result in improving in both Voc and fill factor. The trend in Jsc and η first increases and then decreases. With the dipping time up to 30 min, the nano-composite photoanode coated by SrO and ZnO can further improve the conversion efficiency to 6.91% and 6.56% respectively. Arrays of TiO2 nanowires were prepared by hydrothermal process on a Ti foil.The preparation process and cell performance of arrays of TiO2 nanowires with SrO shell coating are studied. DSSC with Such a novel core-shell structure photoanode improve conversion efficiency, with improving of open circuit voltage, short circuit current an