TiO2基新型催化剂合成及光电催化性能研究-工业催化专业论文.docx

上海师范大学硕士学位论文Ab 上海师范大学硕士学位论文 Abstract 万方数据 万方数据 synthesized assisted with ionothermal method by treating metal Ti in an ionic liquid containing LiAc, HAc and H2PtCl6 aqueous solution under mild ionothermal conditions. The photocatalytic activity was enhanced for H2 evolution due to the various valence states of Pt forming Pt0, Ptδ+, Ti3+-dopants, oxygen vacancies and high specific surface area. The synthesized samples were characterized by different techniques such as XRD, XPS, FESEM, TEM, photoluminescence (PL), diffuse reflectance UV-Vis etc. The observed photocatalytic activity of Pt-Ti3+/TiO2 was significantly higher than photo-reduction Pt loading on original TiO2 and commercial P25. And different morphologies of Pt-Ti3+/TiO2 were attributed to the noble metal Pt induced self-assembly forming flower-rods microsphere structure. The defects sites of Ti3+-dopants and oxygen vacancies would be feasible to make the Ptδ+ enter the framework of mesoporous TiO2. A plasmonic Ag/TiO2 photocatalytic composite was designed by selecting Ag quantum dots (Ag QDs) to act as a surface plasmon resonance (SPR) photosensitizer for driving the visible-light driven photoelectrocatalytic hydrogen evolution. Vertically oriented hierarchical TiO2 nanotube arrays (H-TiO2-NTAs) with macroporous structure were prepared through a two-step method based on electrochemical anodization. Subsequently, Ag QDs, with tunable size (1.3-21 nm), could be uniformly deposited on the H-TiO2 NTAs by current pulsing approach. The unique structure of the as-obtained photoelectrodes greatly improved the photoelectric conversion efficiency. The as-obtained Ag/H-TiO2-NTAs exhibited strong visible-light absorption capability, high photocurrent density, and enhanced photoelectrocatalytic (PEC) activity toward photoelectrocatalytic hydrogen evolution under visible-light irradiation (λ 420 nm). The enhancement in the photoelectric conversion efficiency and activity was ascribed to the synergistic effects of silv