中孔镍基催化材料调控制备及在ch4co2重整反应中的性能分析-preparation of mesoporous nickel-based catalytic materials and performance analysis in ch4co2 reforming reaction.docx

下载文档 降价啦

5
0
约11.97万字
约 109页
2018-09-10 发布于上海
举报
版权申诉
保障服务

中孔镍基催化材料调控制备及在ch4co2重整反应中的性能分析-preparation of mesoporous nickel-based catalytic materials and performance analysis in ch4co2 reforming reaction.docx

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。

中孔镍基催化材料调控制备及在ch4co2重整反应中的性能分析-preparation of mesoporous nickel-based catalytic materials and performance analysis in ch4co2 reforming reaction

万方数据万方数据 3. The catalytic ability of catalysts is improved not only by a certain promotor but also by the regulation in the properties of support. In this thesis, novel mesoporous material as support was prepared primarily and the preliminary preparation process, in which CMK-3 prepared by SBA-15 was used as hard template and then metal oxide with mesoporous framework prepared was probed. The results indicated that controlling calcination temperature was particularly important to the stability in structure. Otherwise, the hole wall collapsed easily during calcination. In addition, the high temperature can cause water vapor evaporating quickly and destroy the pore structure. In addition, synthesis of a N3-18-N3 surfacant, which can be used as a template for the preparation of a novel mesoporous materials, was developed primarily in this dissertation. Its structure was characterized by NMR, MS and other techniques. KEY WORDS ： Methane, CH4/CO2 reforming, Nickel, Zirconium, Yttrium, SBA-15, Doping 目录第一章文献综述……………………………………………………………………1 1.1 前言……………………………………………...……………………..1 1.2 甲烷制备合成气……………………………………………………….3 1.2.1 甲烷制备合成气方法…………………………………………..3 1.2.2 CH4/CO2 重整反应机理………………………………………..4 1.3 CH4/CO2 重整反应研究现状 ………………………………………….6 1.3.1 CH4/CO2 重整反应研究的主要方面………………………….6 1.3.2 CH4/CO2 重整反应催化剂的研究现状……………………….8 1.4 催化剂研究的主要成果 ……………...……………………………...10 1.5 镍基催化剂的积碳问题. ……………...……………………………...20 1.6 镍基催化剂的制备方法 ……………...……………………………...22 1.7 本论文的主要工作内容………………………………………………22 第二章镍基催化剂的表征方法及性能测试手段………………….……………24 2.1 催化剂活性及稳定性测试…………………………………...………24 2.1.1 主要试剂及仪器………………………………………………24 2.1.2 催化剂的制备…………………………………………………25 2.1.3 活性测试装置图………………………………………………25 2.1.4 催化剂活性评价………………………………………………26 2.1.5 催化剂稳定性测试……………………………………………27 2.1.6 计算方法………………………………………………………27 2.2 催化剂表征方法…………………………………………...…………27 2.2.1 氮气吸脱附曲线表征（BET）………………………………27 2.2.2 X-射线衍射表征（XRD）……………………………………27 2.2.3 傅里叶变换红外光谱表征（FT-IR）…………………………28 2.2.4 紫外光谱表征（UV）…………………………………………28 2.2.5 透射电子显微镜表征（TEM）…………….…………………28 2.2.6 X-射线光电子