无碱无氯液体速凝剂聚合硅酸硫酸铝制备及机理研究.docVIP

无碱无氯液体速凝剂聚合硅酸硫酸铝制备及机理研究 　　摘 要 利用“水解嵌入聚合”作用将氟硅酸镁与自制聚合硫酸铝（PAS）反应并结合“水解聚合浓缩”同步工艺制得无碱无氯液体速凝剂聚合硅酸硫酸铝（PASS）.实验结果表明，PASS速凝剂在7%掺量时接近喷射混凝土用速凝剂（JC4772005）一级品的指标要求.并通过X射线衍射（XRD）和扫描电子显微镜（SEM）对PASS速凝剂的促凝机理进行了研究. 　　关键词 聚合硫酸铝；氟硅酸镁；聚合硅酸硫酸铝；无碱无氯速凝剂 　　中图分类号 TU528.042.1文献标识码 A文章编号2016 　　Study on the Preparation and Mechanism of Alkalifree and 　　Chlorinefree Liquid Accelerator Polyaluminium Silicate Sulfates 　　JIANG Min， YANG Chunming*， YIN Chengjie， DENG Cuifen， ZHAO Liping， SHEN Ping 　　（ College of Chemistry and Chemical Engineering， Hunan Normal University， Changsha 410081， China） 　　Abstract An alkalifree and chlorinefree accelerator liquid acceleratorpolyaluminum silicate sulfate（PASS） was prepared by hydrolysis and polymerization of magnesium silicofluoride within selfmade polyaluminium sulfate matrix， coupled with the “hydrolysispolymerizationconcentration” threeinone technology. The influence of the mass ratio of magnesium silicofluoride to polyaluminium sulfate， reaction temperature and stirring speed on the performance of asprepared liquid accelerator has also been investigated. Our experimental results show that the resultant liquid accelerator has the same quality close to the firstgrade production of shortcrete accelerator standard JC4772005 when the added amount of accelerator is 7.0%. Comparative studies of cement slurry with added accelerator and blank sample at different hydration stages were conducted by XRD analysis and SEM techniques. A possible coagulation mechanism of liquid accelerator PASS was proposed based on above results. 　　Key words polyaluminium sulfate； magnesium silicofluoride； polyaluminium silicate sulfates； alkalifree and chlorinefree liquid accelerator 　　速凝剂是一种能促使水泥在较短的时间内凝结硬化，并产生一定抗压强度的水泥外加剂.速凝剂是喷射混凝土施工中不可缺少的添加剂，主要应用于一些具有特殊要求的工程施工，如道路抢修、矿山、隧道、矿井巷道、防洪堤坝等工程[1].速凝剂的生产和使用起源于20世纪30年代[2]，从最早的高碱粉末速凝剂发展到如今的无碱液体速凝剂[36]，但是无碱速凝剂存在掺量高、稳定性差等问题，不利于全面推广[78]. 　　无碱速凝剂的主要成分之一为铝盐，当铝盐含量过高时容易析出Al（OH）3沉淀，因而需要加入大量的稳定剂[910]，但是稳定剂的量过大对促凝起消极作用.作