无电压作用离子交换膜分离去除水中锰离子研究.docVIP

无电压作用离子交换膜分离去除水中锰离子研究 　　摘要:研究了离子交换膜在无外加电压的条件下分离去除原水中锰离子的技术,探讨了锰离子浓度、补偿离子钾离子摩尔浓度、水力搅拌速度、温度和水力停留时间(HRT)等对去除效果的影响.实验结果表明,当原水中二价锰离子初始摩尔浓度为0.0727mmol/L(即4mg/L)左右时,在下述的实验条件下:水温为(25±1)℃,水力停留时间HRT为6h,水力搅拌速度为(600±25)r/min,补偿离子钾离子的摩尔浓度是原水中锰离子摩尔浓度的20倍,锰离子去除率达到80%.此外,在实验装置不改变的条件下,进水锰离子摩尔浓度增加到0.727mmol/L(即40mg/L)左右时,去除率会降低到66%;补偿钾离子摩尔浓度与进水锰离子摩尔浓度的比值大于20后,再增加其比值,对去除率影响不大;降低搅拌速度到(300±25)r/min,去除率降低到51%;降低水温到(16±1)℃,去除率降低到60%;水力停留时间(HRT)大于6h后,再增加水力停留时间到12h,去除率无明显改变. 　　关键词:离子交换膜;唐南分离;重金属;锰离子 　　中图分类号:X505文献标识码:A 　　StudyoftheRemovalofManganesefromWaterwithanIon??exchangeMembranewithoutExternalVoltageApplication 　　XIEDe??hua????1,2?k??,SHIZhou??1,CHENShi??yang??1,XIEPeng??1,SONGyong??1 　　(1.CollegeofCivilEngineering,HunanUniv,Changsha,Hunan410082,China;2.CollegeofCivilEngineering,HunanUnivofScienceandTechnology,Xiangtan,Hunan411201,China) 　　Abstract:Theremovalofmanganeseionfromwaterwithanion??exchangemembraneundernoexternalvoltageconditionwasstudied,andtheeffects,suchasmanganeseionconcentration,theconcentrationofcompensationpotassiumions,waterstirringspeed,temperatureandhydraulicretentiontime(HRT)ontheremovalefficiencyofmanganeseionswerealsoevaluated.Theresultshaveshownthat,whentheinitialconcentrationofbivalentionMn????2+??is0.0727mmol/L(4mg/L),undertheexperimentalconditionsofthewatertemperatureof25℃,HRTof6h,hydraulicmixingspeedof(600±25)r/min,andtheconcentrationofthecompensationionK??+is20timesthatofMn????2+??,theremovalefficiencyof80%forthemanganesecanbeachieved.Inaddition,withtheequipmentsunchanged,whentheinletconcentrationofmanganeseincreasesto0.727mmol/L(40mg/L),theremovalefficiencywillbeloweredto66%;whiletheratiooftheconcentrationofcompensationpotassiumionstothatofinletmanganeseishigherthan20,theremovalefficiencywillnotchangesignificantly,iftheratiocontinuestoincrease;byloweringthestirringspeedto(300±25)r/min,theremovalefficiencywillbedecreasedto51%;byloweringthetemperatureto(16±1)℃,theremovalefficiencyis60%;whenthehydraulicretentiontime(HRT)ismorethan6h,theremovalefficie