掺杂Li4Ti5O12锂离子电池负极材料的制备与电化学性能研究-微电子学与固体电子学专业论文.docxVIP

万方数据 万方数据 Abstract Recent years, spinel Li4Ti5O12 has attracted significant attention as a promising candidate of cathode materials for lithium-ion batteries due to its superior cycling stability, outstanding safety performance, low cost and environmentally friendly. However, low electronic conductivity and poor high-rate performance are the main obstacles for the development and commercialization of Li4Ti5O12. In order to improve the conductivity, rear earth ions doping and metal nanocrystals combination were mainly used to improve the electrochemical performance of Li4Ti5O12. Li4Ti5O12 nanocrystals were synthesised by the method of hydrothermal method and subsequent annealling process, using tetrabutyl titanate as titanium precursor, lithium hydroxide monohydrate as Li precursor and RE3+ (RE=Gd3+, Y3+, La3+) ions as doped ions. The XRD, Raman, SEM, EDS, TEM results of the saamples with different norminal doping concentrations （ 0% 、 6% 、 10% ） show that the as-synthesized nanocrystals are spinel Li4Ti5O12, and with the increase of RE3+ doping concentration, the thick nanosheets with irregular shape are converted to regular ultrathin nanosheets with a thickness of ~8.5 nm, meanwhile the surface area increase from 32.9 to 43.4 m2g-1. The electrochemical properties of samples with different RE3+ doping concentration through the charge and discharge performance test, cyclic voltammetry and EIS are measurd, indicating that the Li4Ti5O12 naosheets doped with RE3+ show better electrochemical performance. For example, when the doping concentration of Gd3+ increase to 10%, the ultrathin nanosheets with nominal doping concentration of 10% show the initial discharge capacity of 175.88mAh/g at the current rate of 1C, capacity kept at 164.83mAh/g after 100 cycles, and high discharge specific capacity retention rate as high as 93.7%. II In order to further improve the electrochemical performance of Li4Ti5O12 materials, the Li4Ti5O12/Ag composite materials was prepar