掺杂P91铁素体耐热钢蠕变性能的分析-材料加工工程专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - II- Abstract Before the 1980s, the steam parameter of a conventional generator unit can not be improved effectively around the world due to the limitation of the heat-resisting materials. Since P91 ferritic heat-resistant steel has been successfully developed in 1983, and it began to be widely used in the construction of ultra-supercritical power station for its excellent proprieties. P91 steel was first introduced to China in 1987, and was trial-produced in 1991. Although a certain achievement has been obtained, but due to the weak foundation, the properties of P91 steel made in China can not reach the international advanced standard. The high temperature creep properties of steel play a decisive role in the service performance, and thus the studies on the creep properties of P91 steel affected by impurity elements Sn and S were performed in this dissertation. After S-doped P91 steel and Sn-doped P91 steel were normalized at 1328 K and then tempered at 1033 K, followed by the creep tests which were carried out in the temperature range of 873K~923K and the stress range of 150MPa~210M pa. Based on the creep experimental data, the permanent strengths of the steels were obatined by means of establishing the creep constitutive equation and the Monkman–Grant relation. By comparing the permanent strengths of both steels, it was found that the effect caused by Sn was more seriously. Lots of cavities were found around the creep fracture surfaces for both stteels, but at the same temperature and stress, the number of cavities in the Sn-doped P91 steel was obviously more than that of the S-doped P91 steel. Therefore, compared with S, Sn is more likely to promote the cavities nucleation in P91 steel, leading a more detrimental effect on the creep properties of P91 steel. The morphology, distribution and composition of the second phase in the steels were analyzed by field emission gun scanning transmission electron microscopy (FEGSTEM). It wa