多孔结构及老化时间对铜低密度聚乙烯复合材料力学性能的影响-材料学专业论文.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract The influence of pore structure and aging time on the mechanical properties of Cu/LDPE composite has been studied in this paper. During the research on the porosity, we used DTBHQ, antioxidants 2246, the compound of DTBHQ and antioxidants 2246 (mass ratio is 1:1) as porogen to obtain three kinds of experimental samples of Cu/LDPE porous composite with different porosity (corresponding, respectively, denoted as the PCP series, PCD series and PCPD series). The results show that the mechanical properties of the PCP series porous composites decrease with the increasing of porosity. The elongation at break of the PCD series porous composites increases, the tensile strength and the elastic modulus decrease with the increasing of the porosity and decreasing speed is getting smaller and smaller. The test results of mechanical properties of PCPD series porous composite materials show that the, the greater the porosity, the greater the elongation at break, the smaller the tensile strength and elastic modulus of the porous composites. During the research on the morphology, We used the mass fraction ratios of Antioxidant 2246 and DTBHQ being 0:10, 3:7, 5:5, 7:3 and 10:0, the total mass fraction of the mixture are 30% as the porogen to obtain five kinds of Cu/LDPE porous composites with different pore morphologies (referred to as the PC series). The results of the mechanical properties of the Cu/LDPE porous composites with different pore morphologies show that the elongation at break, the tensile strength and the elastic modulus gradually increased with the increasing of the mass fraction of the antioxidants 2246 added to the sample preparation process during the tensile test. During the research on the aging time, the hygrothermal aging tests have been performance on the Cu/LDPE composite. The mechanical properties after hygrothermal aging have been studied on the Cu/LDPE composite, the results show that with the increasing o