仿生超疏水涂层的制备及性能研究-化学工程专业论文.docxVIP

涂层在多种材料上均具有超疏水性。由于 TiO2 的光敏特性，在紫外光下照射 3~4h 后， 涂层表面接触角由 156°降为 3°，由超疏水性表面变为超亲水性表面；然后将该超亲水 性表面在黑暗处放置 20d，涂层表面又恢复了疏水性，此时接触角为 120°。 由 SEM 照片和接触角测试可知，所制备的二氧化硅/聚硅氧烷涂层表面形貌与荷叶 表面的微-纳米粗糙结构相似，且具有超疏水性。二氧化硅/聚硅氧烷涂层的疏水性跟二 氧化硅与聚硅氧烷质量比有关。当二氧化硅与聚硅氧烷质量比在 1:5~1:6 之间时，涂层 表面具有超疏水性，接触角为 156°，滚动角为 4°。在该质量比范围内采用 7nm SiO2 制 备的涂层除了具有超疏水性外，还有较好的透明性，在可见光范围内平均透光率高于 75%。二氧化硅/聚硅氧烷超疏水涂层粘结强度高，稳定性较好，用测试胶带剥离 5 次后， 涂层表面接触角仍大于 150°，滚动角小于 10°，仍具有超疏水性。而且，二氧化硅/聚硅 氧烷涂层对多种材料均有较好的超疏水性。 关键词：仿生，超疏水性，涂层，二氧化硅，二氧化钛，聚氨酯，聚硅氧烷 The Study on Preparation and Properties of Biomimetic Superhydrophobic Coating Abstract In nature, many animals and plants have superhydrophobic, such as the lotus leaf surface, the water strider legs, butterfly wings. By studying these natural superhydrophobic surfaces, found that these superhydrophobic properties mainly depended on the rough micro-nanostructure and waxy layer of the surface. Therefore, controlling the surface chemical composition and morphology of material can control the hydrophobic of the surface of the material effectively. It provided theoretical basis and design ideas for the preparation of artificial superhydrophobic coatings. According to the characteristics of lotus leaf superhydrophobic surface structure, dispersion solution was prepared by biomimetic method using silica (SiO2), titanium dioxide (TiO2), polyurethane (PU), polysiloxane as raw materials. SiO2/PU superhydrophobic coating, wettability can shift of TiO2/PU superhydrophobic coating, silica/polysiloxane transparent superhydrophobic coating with rough surface similar to lotus leaf, which built by using the spraying process combining phase separation and self-assembly technology. The coating surface contact angle (CA) and sliding angle (SA) of water droplets were determined by contact angle tester. Microscopic structure of the coating surface was observed by field emission scanning electron microscopy (SEM). Stripping experiments of different coatings were carried out by 3M610 type test tape, the change of