仿酶催化剂的合成及其在棉织物印染加工中的应用研究-纺织化学与染整工程专业论文.docx

CuTPEN），并研究了它们在棉织物低温漂白中的催化性能与作用机 理。结果表明，三（2-氨基吡啶）胺铜配合物（CuTPMA）催化剂活 性最好，在其最佳漂白工艺条件下：30% H2O2 10g/L，烧碱 2g/L， CuTPMA 20μmol/L，稳定剂 0.5g/L，精练剂 0.5g/L，70℃，60min， 漂白后织物白度能达到 72%，白度增加了 11%，显示了较好的应用效 果，该仿酶催化剂可将漂白的温度降低到 70℃。对仿酶催化剂的催 化机理研究发现，漂白过程中生成的 Cu(I)TPMA(OOH)是漂白的活性 物质。此催化剂可用于染浅色棉织物漂白过程，具有较好的应用前景。 四酰胺大环类仿酶催化剂同样具有很高的催化活性，本论文合成 了四酰胺大环铁配合物（FeTAML)，并进行了氧化清洗性能研究。实 验发现四酰胺大环铁（FeTAML)仿酶催化剂脱色效果较好，因此将其 应用于棉织物染色后低温清洗中，构建 FeTAML/Na2CO3/H2O2 催化氧 化清洗体系，并研究了其氧化清洗工艺与机理。结果表明，25℃时， 加入 1μmol/L 的 FeTAML 后，8 种活性染料均能迅速脱色，显示了 极高的催化氧化活性。随后利用单因素实验，得到了氧化清洗最佳工 艺条件，30%H2O2 0.8g/L，Na2CO3 1.5g/L，FeTAML 3.2μmol/L，温度 为 50℃，清洗时间 10min。催化氧化清洗后棉织物各项指标与常规皂 洗相当，湿摩擦牢度还可提高半级，更为重要的是，催化氧化清洗比 常规皂洗的温度降低了 45℃，氧化清洗后残液吸光度与 COD 较常规 皂洗减少了 60%以上。可将此仿酶催化氧化清洗工艺用于棉织物皂洗 中。对氧化清洗机理研究表明，四酰胺大环铁与过氧化氢形成的活性 III 物质对未成键染料的氧化速率远远大于成键的染料，从而可以实现选 择性氧化清洗的效果。 关键词：金属配合物；仿酶催化剂；催化氧化；低温漂白；低温清洗 IV SYNTHESIS OF BIOMIMETIC ENZYME CATALYSTS AND THEIR APPLICATION ON DYEING AND FINISHING OF COTTON FABRICS ABSTRACT Biomimetic enzyme catalysts are non-protein catalysts which imitated the important activity metal center and ligands of natural enzymes. Biomimetic enzyme catalysts have many advantages, such as easy preparation, high stability, small dosage, and does not produce toxic or harmful by-products in the reaction process. They have been used in pulp bleaching and washing clothes but less used in printing and dyeing processing. Under this background, this paper synthesized four categories of a total of 19 biomimetic enzyme catalysts according to imitated the main structure of peroxidase. The application and mechanism of these biomimetic enzyme catalysts in bleaching and washing off cotton fabrics at low temperature were studied in detail. The aim of this paper is to lower the temperature of the printing and dyeing processing and achieve good application effects. At the same time, this paper can further guide the development of more efficient biomimetic enzyme catalysts. First of all, six kinds of porphyrin/phthalocyanine metal complexes were s