无机化学（张天蓝）cu教学材料.pptVIP

Chap21. Copper;铜副族元素在周期表中的位置;;Why cuprous（亚铜离子） can’t be stable in water？;Sodium ion surrounded by water, attracted by electrostatic attraction;也是配合物;对[Cu(H2O)4]SO4·H2O结构的解释有两种：;the artist， 2008, Roger Hiorns;Atomic Radii Of The TM’s Elements;[Cu(H2O)4]2+ ? [Cu(H2O)3(OH)]+ ＋H+ ;检验糖尿病：红色为有病，蓝色没有病;;OXIDATION and REDUCTION;Cu(I)/ Cu(II)转化的影响 ;2Cu2+(aq) + 5I-(aq) ═══ 2CuI(s) ↓ + I3-(aq) ;2Cu2+(aq) + 5I-(aq) ═══ 2CuI(s) + I3-(aq) + Na2S2O3(aq) I- + S4O62-;Question ; Cu2+ + e→ Cu+ E? Cu2+/Cu+ = 0.152V Cu+ + e→ Cu E? Cu+/Cu = 0.521V 2Cu+ = Cu2+ + Cu(s) ;;The formation, transformation and eliminate of Reactive oxygen species;Bleomycin is a DNA cleaving antibiotic and anti-cancer drug; 导致DNA链的断裂原因是由于博来霉素分子的一部分是铁或铜的配合物，这类配合物能够产生导致DNA链断裂的自由基。;Check Point 请总结类Haber-Weisz反应发生的条件;EA0 O2 HO2 . H2O2;;铜离子catalyze 的O2 .- Disproportionation反应;;Copper participates in reactions reactive oxygen species (ROS) producing reactions :;Complexation of cupric and cuprous;浅蓝; 配合物的杂化成键过程;Jahn-Teller effect;The d-orbitals:;Splitting of the d sub-shell in octahedral coordination;Crystal Field Stabilization Energy (CFSE):;Structural effects of Jahn-Teller distortion; ;压扁的八面体;拉长的八面体;; For M(II) ions with the same set of ligands, the variation of Δ is not large. One can therefore use the equation for CFSE to calculate CFSE in terms of Δ for d0 through d10 M(II) ions (all metal ions high-spin): Ca(II) Sc(II) Ti(II) V(II) Cr(II) Mn(II) Fe(II) Co(II) Ni(II) Cu(II) Zn(II) d0 d1 d2 d3 d4 d5 d6 d7 d8 d9