催化蒸馏构件的流体力学性能研究-化学工艺专业论文.docxVIP

中文摘要 催化蒸馆技术是化工过程绿色化的重要手段之一，催化蒸馆技术的关键之~ 是如何将固体催化剂布置于催化蒸馆塔中，以使催化反应和蒸惰分离都能高效进 行。为此，科技工作者开发了众多催化剂装填方式和构件以解决该问题。本文研 究了两种催化剂装填方式(构件)的性能，它们分别是传统的捆扎包式催化剂装 填方式和本课题组研发的惨流型催化蒸馆构件。 ‘ 本文研究了不同催化剂装填量下使用捆扎包式装填的催化蒸馆塔流体力学 性能和分离性能。研究发现，采用捆扎包式装填的催化蒸馆塔服降比常规精饱塔 -‘ 大，且随着所装填催化剂量的增多，压降增大有加剧的趋势。另一方面采用捆扎 包武装填的催化蒸馆塔持液量较常规蒸馆塔偏大，这是导致其压降增大的一个原 因，但同时，较高的持液最对于催化反应是布利的。研究还发现，采用拥扎包武 装填的催化蒸馆培分离性能比常规蒸馆塔低。 本文震点研究了本课题组开发的楼流型催化蒸馆构件，详细阐述了该构件的 概念、优点和应用方式，特别地，以过滤模型和潘流理论为基础建立了惨流型构 件的理想模型。分别以水、乙醇、汽油、轻汽油、重汽油为物系，对渗流型构件 进行冷模流体力学研究，为构件的放大设计和工业应用提供了可靠的基础数据。 本文还对楼流型构件的持液量问题进行了初步的讨论，对惨流型构件的工业应用 具有指导意义。 关键词: 催化蒸馆、催化蒸馆元件、捆扎包构件、楼流型构件、流体力学性 句 可. ABSTRACT Catalytic distillation is an important technology for en町gy saving and process intensification in chemical engineering processes. One of 由e keys to catalytic distillation is how ωlayout the solid catalyst in catalytic distillation column ωmake both c剖alytic reaction and distillation separation be carried on effectively. Scientists have developed several methods ωsolve 由e problem including structures of catalyst -... packings. In也is work， two sorts of catalyst packing were studied involing conventional bale-type packings and permeable catalytic packings developed by 0町 、 group recently. h 由is work， hydrodynamic and s叩aration p町formance of 由e catalytic distillation column using bale句pec创alyst packings wi由different amount of catalyst loading were studied. As a result，we found 曲创 the press旧e drop of the catalytic distillation column with bale-type catalyst packings wωl町g町也an that of the conventional distillation column，and wi白白e increase in 也e amount of catalyst loading，pressure drop increased. One reason is higher liquid holdup in 伽is catalytic distillation column compared with that 扭曲e conventional distillation columns. Howev町 higher liquid holdup is beneficial for the cataly甘c reaction. The s阳dyalω found 由刨出e sep町ation efficiency of the catalytic distillation column is lower than the conventional distillation column，because the catalyst particles occu