催化臭氧氧化处理含菲废水特性及工艺研究-环境工程专业论文.docxVIP

Abstract Anthracene and phenanthrene without branch PAHs was listed as priority pollutants in the United States, in our country phenanthrene etc also listed as in priority pollutants in 14 categories.Thus,in recent years,a concern has been growing about PAHs release,amount,stability,and fate in the environment.PAHs often detected from kind discharged wastewater of variety industrial. total content of PAHs is 20~30 μg/L, content of phenanthrene is 6~17μg/L. And our country drinking water standards for PAHs limit is 2μg/L, In America surface water area, The content of carcinogenic PAHs with the allowable value is 2.8×10-3μg/L. This paper studied supported catalyst with different metal and carrier, which catalytic ozonation trace phenanthrene efficiency from water. Influence factors of ozone reaction with simulated of trace phenanthrene alone, choice the best catalysts and optimize parameter,A/O- catalytic oxidation process and MBR process continuous trentment actual wasterwater of dyes contain phenanthrene were investigated in this papers,and the main results are as follows: This paper using impregnation method made one-metal and two-metal catalysts, Through the SEM and spectrometer characterization results show that the metal load effect is good, the Haydite supported Mn catalyst were characterized by SEM and energy spectrum, and the results show that Mn content about 3%. characterization results that Haydite supported Mn and Ni show that metal oxide in haydite surface are distributed uniform, and Mn capacity at 2~3%, and Ni content is 2~4%; Studies the Discusses the effect of ozone oxidation phenanthrene alone, the results show that, when the concentration of phenanthrene is 24μg/L, pH in 7.8, ozone dosing of speeding rate is 360μg/min, reaction 4 min, phenanthrene removal rate achieved stability, above 95%. Among the one-metal supported catalyst,Haydite supported Mn catalyst for ozone catalytic effect is best.Phenanthrene concentration of simulation wa