纯钛表面基于微弧氧化技术的仿生陶瓷膜的制备、表征及性能分析-材料加工工程专业论文.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 IV IV treatment, the amorphous phases were tested to be HA and calcium phosphate ceramics. Calcination treatment has made the coating thicker and made the heat cracks deeper and wider. The ratio of Ca/P of this coating then is bigger than that same ratio of natural HA. Although the element of La did not form any new phase within the film, it played an important role in facilitating the formation of HA: it caused unbalanced electron charge, which led the TiO2 water gel to form and later prompted the formation of HA. According to the results of adhesion test, the adhesion of coatings performs better after the hydrothermal treatment; the adhesion of coatings gained from electrolyte with La performs better than that from electrolyte without La, but the calcination treatment makes the adhesion poorer. According to the results of corrosion resistance, all the coatings gained from MAO treatment with or without later treatment have better corrosion resistance performance than pure titanium. After the hydrothermal treatment, the MAO coating performs poorer corrosion resistance; while the calcination treatment, the coating gained from electrolyte with La exhibits better corrosion resistance. Cell-culture is used to compare the cyto-compatibility of four kinds of coatings prepared in this paper as well as pure titanium. The results show that all the coatings have better cyto-compatibility than pure titanium. Hydrothermal treatment can improve the cyto-compatibility performance of coatings, while calcination treatment to some degree lower the cyto-compatibility performance of coatings. Key words：Titanium；Micro-arc oxidation(MAO)；Hydrothermal treatment；Calcination treatment；Hydroxyapatite (HA)；Corrosion resistance；Cyto-compatibility 独创性声明 本人声明所呈交的学位论文是我个人在导师指导下进行的研究工作及取得的研 究成果。尽我所知，除文中已经标明引用的内容外，本论文不包含任何其他个人或 集体已经发表或撰写过的研究成果。对本文的研究做出贡献的个人和集体，均已在 文中以明确方式标明。本人完全意识到本声明的法律结果由本人承担。 学位论文作者签名： 日期： 年 月 日 学位论文版权使用授权书 本学位论文作者完全了解学校有关保留、使用学位论文的规定，即：学校有权 保留并向国家有关部