改性活性炭吸附含水气的甲苯废气的性能研究-环境工程专业论文.docxVIP

西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 Study on performance of modified activated carbon adsorption of toluene waste gas containing water vapor Specilty: Environmental Engineering Name: Shupeng Zhang Instuctor: Professor Xuemin Huang ABSTRACT VOCs (Volatile Organic Compounds) is one of the worst pollutants for the atmospheric environment in China. In May,2010, the General Office of the State Council put forward a requirement for strengthening prevention and control of VOCs, which put VOCs and SO2, NOx, particulate matters together to be the optimal control conditions for improving atmospheric environment. Adsorption method is one of the most effective to control emissions of VOCs from industrial fixed sources, and it cost less than other processes. However the fixes industrial emission of VOCs has a large relative humidity, amonnts vapor mixed in waste gas have a significant impact on the performance and regeneration of the activated carbon. After reading a large number of relevant literatures, the author chose cheap commercial activated carbon using coal materials, modified them with low concentration acid/alkali solution, change the surface properties of active carbon by loading acid/alkaline functional groups on it. Evaluate performance by dynamic adsorption that utilize modified activeed carbon as adsorbent and toluene as adsorbate. Through the series of experimental and analysis the data to find a modified condition to active carbon that has the top performance for removing toluene in mixed gases with amount of vapor. The experimental results show that the specific surface area of the modified activated carbon samples are becoming larger first and then smaller as the solution concentration rises. Especially, the specific surface area of the sample modified by 1% NaHCO3 is 1035.67m2/g, increased by 18.01% than the original sample. When solution concentration is very low, attachments on commercial activated carbon are dissolved by acid or alk