镉和铅在金属钛酸材料修饰电极上的电化学传感研究分析化学专业论文.docxVIP

II II 的溶出峰电流与其浓度在 6.0×10-8 ~ 1.6×10-5 mol/L 范围内具有良好的线性关系， 检测限低至 4.9×10-9 mol/L。最后用该方法成功测定了实际水样中 Cd (II)含量。 （4）制备了一种钛酸钡、十二烷基硫酸钠（SDS）与 Nafion 复合膜修饰玻碳 电极，利用线性扫描溶出伏安法对 Pb (II)进行了测定。结果表明 Nafion/SDS/BaTiO3 复合修饰电极在测定 Pb (II)时呈现出好的选择性和高的灵敏度。在各项优化实验条 件下，Pb (II) 的阳极溶出峰电流与其浓度在 8.5×10-9 ~ 4.2×10-6 mol/L 范围内具有 良好的线性关系，在-1.00 V 处富集 3 min 后，检测限低至 4.9×10-9 mol/L（S/N = 3）。 最后用该方法成功测定了实际水样中 Pb (II)含量。 关键词：重金属；金属钛酸；离子液体；化学修饰电极；电化学传感器 III III Abstract Environment pollution is increasingly severe coupled with the rapid economic growth, a large number of industrial waste water discharge and heavy metal accumulation intensifying in soil and water. It is a serious threat to biodiversity and the health of human beings that heavy metal can enrich through the food chain and biological. Hence, it is an urgent task to develop rapid and efficient methods for the detection of heavy metals. Ionic liquids (ILs) are liquid electrolytes composed entirely of ions in the room temperature or adjacent temperature. Strong solubility, high conductivity and viscosity, almost negligible vapor pressure, Low toxicity, wide electrochemical potential windows and high chemical and thermal stability make ionic liquids suitable for many applications in the elctrochemical area. Most titanium acid salt materials which are dielectric body can cause the polarization phenomenon under the action of electric field. Strontium titanate and barium titanate with perovskite structure have many good characteristics, such as good catalytic performance, high chemical stability and strong ion absorbility, etc. Current studies have shown that metal titanate materials have strong adsorption toward heavy metals, it can be used for the detection of the heavy metal ions. In this paper, an electrochemical sensor based on strontium titanate adsorption materials and ILs with good conductivity composites has been developed, and has been successfully applied to the determination of heavy metal ions such as