钙钛矿型载氧体的微波合成与晶体结构研究-热能工程专业论文.docxVIP

II II 华 中 科 技 大 学 硕 士 学 位 论 文 Abstract The emission of CO2 into the atmosphere has been reported to account for half of the greenhouse effect that causes global warming. Oxyfuel combustion is a promising technology which simplifies the flue-gas treatment and has the potential for composing a zero CO2 emission process. Nevertheless, reducing the cost of oxygen production is a key to make the oxyfuel combustion power plant a viable future option when carbon dioxide capture becomes a necessity. Mixed electronic and ionic conducting perovskites have a promising future in the use of sorbents for air separation at high temperature. A new method which used a perovskite ceramic sorbent to produce an O2-enriched CO2 stream is proposed. The microwave irradiation has been shown to provide a economical ,novel and rapid method of preparing many important materials. Microwave processing is a self-heating process that occurs through the absorption of electromagnetic energy. Since the microwave energy is directly absorbed by the sample, uniform and rapid heating can be achieved within a short period of time. A series of BaxSr1-xCoyFe1-yO3-δ perovskites, having important applications, have been successfully synthesized by two different methods, namely microwave assistant-citrate and citrate-EDTA complexing method. The X-ray diffraction (XRD) was used to characterize the phase homogeneity and the particle morphology was observed by Environment scanning electron microscope (SEM). Study of different preparation methods on the perovskite-type oxide oxygen release performance has the following results. XRD analysis confirms that all samples prepared in both methods are of perovskite-type structure. The samples synthetized by microwave method have smaller particle size. SEM micrographs suggest that The samples synthetized by microwave method have a porous structure and the samples synthetized by citrate-EDTA carry a dense structure; the particle size is much smaller than that III III 华 中