CoPcCOOH8SAmCS双极膜的制备及表征.docVIP

CoPc_COOH_8_SA_mCS双极膜的制备及表征 物理化学学报(Wuli Huaxue Xueba) o December 2438 Acta Phys. -Chim. Si2009,n., 25(12):2438-2444 [Article] CoPc(COOH)-SA/mCS 双极膜的制备及表征 8 1,2,11*11 震 曦 晓 陈日耀 陈郑陈黄彩霞 1 2 (福建师范大学化学与材料学院, 福州 350007; 宁德师范高等专科学校化学系, 福建 宁德 352100) 3+摘要: 分别用 Fe离子和戊二醛作为交联剂对海藻酸钠(SA)阳膜层和壳聚糖(CS)阴膜层进行改性, 制备了八羧 基钴酞菁-海藻酸钠/改性壳聚糖(CoPc(COOH)-SA/mCS)双极膜 (BPM). 在海藻酸钠阳膜层中添加八羧基钴酞菁 8 以提高阳膜的离子交换容量, 促进中间层水的解离. 用傅立叶红外(FT-IR)光谱、扫描电镜(SEM)等方法对制备的 +双极膜进行了表征. 实验结果表明, 经八羧基钴酞菁改性后, 阳离子交换膜层的离子交换容量、H离子透过率均 3+获得提高. 与 Fe离子改性或二茂铁离子改性的 mSA/mCS双极膜相 比, CoPc(COOH)-SA/mCS双极膜的交流阻 82 -抗、电阻压降(IR 降)和溶胀度降低. 当电流密度高达 105 mAcm时, CoPc(COOH)-SA/mCS双极膜 的 IR 降仅 ?8 为 0.7 V. 关键词: 双极膜; 八羧基钴酞菁; 海藻酸钠; 壳聚糖; 中间界面层; 水解离 中图分类号: O646; O614.12 Preparation and Characterization of CoPc(COOH)-SA/mCS 8 Bipolar Membranes 11,2,11 1*CHENR i-Yao CHENZhe n ZHENG Xi CHENXi aoHUANG Cai-Xia 1(Collegeof Chemistry and Materials Science, Fujian NormalUn iversity, Fuzhou 350007, P. R.Ch ina; 2Chemistry Department, Fujian Ningde Teachers College,Ningde 352100, Fujian Province, P. R.Chi na) Abstract: A sodium alginate (SA) cation layer wasm odfiied by cobalt octocarboxyphthalocyanine (CoPc(COOH)) 8 to mprove ts on exchangea cpacty and to promote wastperltt ng at the nterayer. The CoPc(COO-HS)A andh citosan iiiiiiil83+ (CS) were thenmod fiied using Feand glutaraldehyde asli nking reagentsto prepare CoPc(COO-SHA)/mCS b ipolar 8 membranes (BPMsF)T.- IR spectra and SEM were usedto ch aracterze CoPc(COOH-)SA/mCS BPMs. Expermentaiil 8 results showed that itonhe exchange apcacity and hydrogenion transmigration rate of the CoPc(COOH-S)A action 83+ exchange membrane ihncarde ased. By comparison to the mSA/mCS BPM that mwaodsfi ied by Feor ferrocene, the AC impedance, IR drop and thesw elling degreeof the CoPc(COOH-S)A/mCS BPMsall decreased. The IR dofrop the 8-2CoPc(COOH-SA)/mCS BPM was onlyV 0.at7 a higher currentns deity of 105 mAcm.? 8 Key Words: Bipolar membrane; Cob alt octocarboxyphthalocyanine; Sodium alginate; Chitosan; In terlayer; W