聚氨酯增韧回收聚苯乙烯的研究 文献综述.docVIP

聚氨酯增韧回收聚苯乙烯的研究+文献综述 摘要： 以马来酸酐接枝的聚苯乙烯（PS）为增容剂，通过密炼机熔融混合，制备了不同改性配比的氨纶/PS共混物，研究了不同的聚氨酯添加量对聚苯乙烯物理、力学性能的影响。研究结果表明改性五（即：聚氨酯、增容剂、PS原料分别为5、20、75份）的综合性能较好，其断裂伸长率为3.52%，提高了0.88%，拉伸强度提高为51.74Mpa，提高了1.48 Mpa，弯曲强度为49.61Mpa，减小了6.22Mpa，冲击强度为3.51 KJ/m2，减少了0.22 KJ/m2。此外，改性五的熔融指数较PS原料（6.042g/10min）有所上升，为6.048g/10min。这说明改性五在成型时流动性较好。并且改性五的玻璃化转变温度相对于PS原料（139.2℃）有所增加，提高到145.3℃。而维卡热变形温度分析表明改性PS的热变形温度变化幅度较小，都在90℃上下波动。5569 关键词： 聚氨酯；马来酸酐；接枝；聚苯乙烯（PS） Study on toughening and recycling PS with polyurethane Abstract：The polyurethane/PS blends with different ratios of polyurethane, bulking agent and PS was prepared by mixer using Maleic anhydride grafted polystyrene (PS) as a bulking agent. The physical and mechanical properties, morphologies of samples with different content of polyurethane were extensively investigated. The experimental results showed that the the modified five (i.e.: Polyurethane, compatibilizer, PS material are 5,20,75phr) have a better integrated performance. Itrsquo;s fracture elongation is 3.52%, increased by 0.88%, tensile strength is 51.74Mpa, increased by 1.48MPa, while Itrsquo;s bending strength is 49.61Mpa,decresed by 6.22Mpa, impact strength is 3.51 KJ/m2, decresed by 0.22 KJ/m2. In addition, the melt index of the modified five is 6.048g/10min higher than PS material (6.042g/10min). This shows that the modified five have a good fluidity during molding. And the glass transition temperature of the modified five increased to 145.3℃, which is higher than PS material (139.2℃). The analysis of the Vicat heat distortion experiment shows that the thermal deformation temperature of modified PS fluctuates around 90℃. 3.2拉伸强度测试8 3.3弯曲强度测试10 3.4冲击强度测试11 3.5熔融指数测试13 3.6维卡软化点（热变形温度）测试15 3.7醇解产物前后胺值、羟值16 3.8断口表面形貌17 3.9动态力学热分析仪（DMA）测定18 4结论22 致谢23 参考文献24 1绪论 聚苯乙烯(PS)塑料是指大分子链中包含有苯乙烯的一类塑料，PS自20世纪30年代工业化生产以来，由于其生产工艺简单且制品的综合性能优良、易加工、价格低、用途广泛并可回收等优点, 而成为当今四大通用聚烯烃材料之一。PS的结构特点是大分子主链为饱和烃类聚合物，侧基为体积大的苯环，因而PS具有良好的电性能、化学性能、拉伸性能、刚性、尺寸稳定性和较高的硬度。然而，也正是侧苯基的存在，使主链骨架上的alpha;一位置上的氢原子活化，在空气中