高密度聚乙烯聚甲醛原位复合材料结构与性能研究-材料加工工程专业论文.docxVIP

重庆理工 重庆理工大学硕士学位论文 摘要 万方数据 万方数据 加相容剂之后 HDPE 与 POM 微晶尺寸得到细化。（2）利用自制口模对三元共混体系 进行挤出成型，结果发现：HDPE/POM/MPEG(80/20/0.7)拉伸强度达到 39.89MPa，与 注塑成型相比，拉伸强度提高了 52.44% ； DSC 结果显示， 与注塑成型相比， HDPE/POM/MPEG(80/20/0.7)共混物 HDPE 熔融峰向高温漂移，漂移变化量为 2.64℃； 对 XRD 衍射（101）晶面数据分析发现，POM 晶粒细化。 综上所述，在 HDPE 基体中添加一定量的 POM，使 HDPE/POM 共混体系的综合 性能得到改善，添加少量的 MPEG，有利于改善 HDPE 和 POM 相容性，在自行研制 的拉伸口模挤出时，实现了 HDPE/POM 与 HDPE/POM/MPEG 共混体系挤出自增强。 关键词：聚乙烯、聚甲醛、聚乙二醇单甲醚、原位成纤、自增强、结构性能、增 容 II 重庆理工 重庆理工大学硕士学位论文 Abstract Abstract In recent years, high density polyethylene (HDPPE) has become the research focus because of the demand for high-performance polyolefin material is on rise year by year. Meanwhile, study of modification of polyformaldehyde (POM) which is used as the commonly used engineering materials is being paid more and more attention. This study aims to achieve a new type of high-performed engineering material by synthesizing the advantages of high density polyethylene (HDPE) and polyformaldehyde (POM). So, in this study, rheology matching of different raw materials was firstly studied the blending material。 And then the best of POM and HDPE was shaped through injection molding. On the basis of the study, extrusion molding by a self-designed convergent forming die, after which structural performance of HDPE/POM blends and HDPE/POM/MPEG blends was further studied. In the dynamic rheological experiment, the rheological properties of HDPE and POM were investigated by Rotational Rheometer. The results show that: (1) the magnitude of the storage modulus and loss modulus of HDEP are inversely related to its relative molecular mass and flowability (MFR); (2) according to the fitting results of the polymer blends, the in-situ reinforcement effect is related to the flowability, when the D-value of MFR is 7~9, the in-situ reinforcement effect would be best. So, 5000S of HDPE and M90 of POM would be the best choice for the blend system. After injection molding and extrusion molding of HDPE/POM blends, the result