AuFe2O3TiO催化剂的制备 表征及催化CO氧化性能研究.docxVIP

优秀毕业论文 精品参考文献资料 摘要摘要 摘要 摘要 本文以Ti02NTs为载体制各了一系列负载型Au—Fe203／Ti02催化剂。采用 ICP．OES，XRD，HR．TEM，UW-vis DRS等测试方法对样品的微观结构进行了 表征。利用微反．色谱装置评价了样品对CO氧化反应的催化活性以及稳定性， 确保了催化活性和稳定性的同时提高。主要研究工作如下： (一)浸渍条件的探讨：采用浸渍法，通过改变浸渍条件，制备7种不同 的Au．Fe203／Ti02催化剂，并对其催化CO氧化活性进行了比较，找出合适的浸 渍条件。结果表明：选择水热法制备的Ti02NTs为载体；FefN03)39H20为金属 氧化物前驱体；用水热法和浸渍法相结合的方法，水热法、还原法和浸渍法相 结合的方法，共沉淀法、水热法和浸渍法相结合的方法制备的Au—Fe203／Ti02催 化剂催化活性良好。 (二)采用水热法和浸渍法相结合的方法两步制备了催化剂Au．Fe203／Ti02。 结果表明：样品为锐钛矿型，Au粒径约为3．5 nlTl，均匀且分散性良好。Fe203 对Au的修饰作用使Au．Fe203／Ti02的活性和在存放条件下的稳定性都有相应提 高。Au含量为1．443 wt．％，浸渍液pH=4，焙烧300℃．2 h的样品催化活性最好 (Tloo=25 oc)。 (三)采用水热法、还原法和浸渍法相结合的方法三步制备了催化剂 Au．Fe203／Ti02。结果表明：样品为锐钛矿型，呈管状结构，形状规则，Au粒径 在3．5 nnl左右、均匀且有很好的分散性。Fe203对Au的修饰作用使Au．Fe203／Ti02 催化剂的活性、在存放条件下的稳定性和热稳定性：部得到提高。当样品Au含量 为2．166 wt．％，Au．sol事先制好时，所得Au．Fe203／Ti02催化剂的催化活性最好 (Tloo=20 oc)。 关键词：Au．Fe203／Ti02，纳米管，低温催化CO氧化，稳定性 AbstractIn Abstract In this thesis，Ti02NTs were prepared by hydrothermal method and then used as the support of Au．Fe203／Yi02 catalysts which have been prepared via impregnation memod．The catalysts were characterized by means of ICP-OES，XRD，HR-TEM， and UV．vis DRS for their composition，crystal phase，morphology and SO on．Their catalytic Derformance were evaluated detailedly by using a microreactor-GC system· The impacts of impregnation conditions，type of the support，metal oxide，pH value， 901d content，calcination temperature upon the catalytic performance of the prepared Au．Fe203／Ti02 catalysts have been discussed deeply Ensure that the samples could exhibit high activity and good stability for low—tempel’atui’e CO oxidation·The main work could be summarized as follows： 1．Discussion of the impregnation conditions：Au-17e203／Ti02 catalysts were prepared by impregnation method with seven different impregnation conditions·The catalytic activities of the as．prepared seven catalysts were compared．The results showed that： The Au．Fe203／Ti02 catalysts which selected Fe(N03)3。9H20 as the precursor of Fe203：Ti02NTs as the carrier；synthesized by the combined of