酸雨对泰山古碑石刻侵蚀的模拟研究.docVIP

酸雨对泰山古碑石刻侵蚀的模拟研究? 孙明虎1，李鹏辉1，张志珍2，王艳1*，王文兴3 （1.山东大学环境科学与工程学院,山东 济南 250100；2.潍坊市环境监测中心站，山东 潍坊 261014； 3.山东大学环境研究院，山东 济南 250100） 摘 要：为研究我国华东典型山地地区的酸沉降对文物古迹的影响，选取与泰山古碑石刻材质相同的花岗石，采用pH分别为3.0、3.8、4.7、5.6的人工模拟酸雨对泰山花岗石进行周期浸泡实验，测定不同pH值下的腐蚀速率；同时利用扫描电子显微镜（SEM）观测试验前后样品表面特征；并对浸泡前后的样品表面粉末进行X射线衍射分析。实验结果表明：影响石材腐蚀的主要因素是酸雨的酸度；花岗石石样受到侵蚀后，质量减少百分数随pH值降低而增大，最大质量损失达到0.073%，而当pH值大于3.8时，石样的最终腐蚀情况基本一致，基本在0.02%左右;并且无论是高酸度酸雨，还是低酸度酸雨，都对材料外观造成了损害;蚀后样品查出了CaSO4和MgSO4相分。 关键词：泰山、花岗石、酸雨、腐蚀、古碑石刻 Deterioration of historic carved stone at Mount Tai By simulated acid rain SUN Ming-hu1, LI Peng-hui1, ZHANG Zhi-zhen2, WANG Yan1?, WANG Wen-xing3 (1.School of Environmental Science and Engineering, Shandong University, Jinan 2. Weifang Municipal Environmental Monitoring Center Station, Weifang 261014, China 3. Environment Research Institute, Shandong University, Jinan 250100, China) Abstract: For the study of east Chinas acid deposition on the impact of cultural relics, materials with the same Mount Tai carved stone were selected. Simulated periodical immersion experiments were carried out by applying artificial acid rain with pH index of 3.0, 3.8, 4.7 and 5.6 onto stone until ten cycles. Rates of deterioration were obtained. The facial characteristics were observed through SEM (Scanning Electronic Microscope), and X-ray diffraction analysis was used to analyze the powders from the samples’ surfaces before and after immersion. Laboratory results indicate that, the acidity is a major factor on the impact of granite stones; after the corrosion, the quality reduction percentage reduces along with the pH increases, maximum mass losses up to 0.073%, but when the pH is greater than 3.8, the eventual corrosions reach basically the same situation, mass losses about 0.02%; and whether it is high acidity or low pH, it has created the harm to the material ; After the corrosion, CaSO4 and MgSO4 have been found out in the samples. Keywords: Mount Tai, granite stone, acid rain, deterioration, historic carved stone 酸雨是当今世