基于FTIR的环境气体监测系统研究-生物医学工程专业论文.docxVIP

中文摘要随着人们对生存环境尤其是生活环境和生产环境的要求不断提高，空气质量 中文摘要 随着人们对生存环境尤其是生活环境和生产环境的要求不断提高，空气质量 问题备受关注，因此需要对环境气体进行有效的监测。而传统的空气污染物监测 方法或者局限于监测‘丽种特定的有害气体，或者需要借助化学试剂，无法做到 实时监测。本课题选择基于傅里叶变换红外光谱(FTIR)技术进行抽气式环境 气体监测，意义在于该方法可以快速的对空气质量和环境污染事故进行多组分同 时监测。 本课题作为低浓度气体(ppm～ppb量级)FTIR检测的基础性研究，从红外 吸收光谱的原理出发，给}_H用于气体浓度求解的理论公式和技术路线。针对待测 对象浓度低，信号弱的特点，从光学系统组成及测量参数、长光程的实现、标准 光谱的制作和光谱分析波数范围的选择等方面进行了优化。重点通过光谱结构分 析和信息挖掘，利用光谱差减方法和标准谱拟合方法对常见空气污染物的多组分 体系进行定量分析，并得到较为满意的结果，相对误差能够控制在士10％以内。 最后提供r实际系统的构成，通过实验设计和结果分析，得到了保证朗伯一比尔 定律有效的浓度光程积的范围和系统的最佳光程长，并利用噪声水平和最低检测 限等指标，对系统性能进行，评价。 本论文利用■维相关红外光谱，提出了一种新颖的最优定量波数区间选取方 法，并与传统的分析谱带选取的原则和实验结果进行，对比，证明r方法的有效 性。 关键词：环境监测傅里叶变换红外光谱光谱分析波数选择 Along Along with the development of economic and the improvement of technique and living level．the subject‘iAir quality”has gained more attention than ever all over the world．At present，most of the traditional systems operated have some disadvantage for real time air quality monitoring．So we try to develop a set ofextractive air quality monitoring system based on Fourier Transform Infrared(FTIR)spectroscopy,which Can in-time measure gaseous air pollutant concentrations． As the basic research ofFTIR applied in low-concentration range(ppm to ppb)gas measurements，this paper provided the gas concentrations retrieving theory and approach．Many measures are utilized to overcome the disadvantage of poor signal intensity．This investigation discussed some issues in details，such as the system configuration，the long path gas absorption cell，how to acquire proper reference spectra，and the collection of optimal wavenumber range．Through spectral analysis， two methods are used to acquire the concentrations from sample spectra．One is spectrum subtraction；the other is criterion spectra fit The result errors call be controlled in土1 0％．Some experiments have been designed to get the product of concentration and path length，the optimal path length for the system，and the performance evaluation． Specially,two—dimensional infrared correlation spectroscopy(2D-IR)tech