基于FTO催化膜电极的制备及其在COD测定和抗生素降解中的应用研究-化学工程与技术专业论文.docxVIP

Ab Abstract Title: PREPARATION OF CATALYTIC FILM ELECTRODE ON FTO AND ITS APPLICATION IN THE DETERMINATION OF COD AND DEGRADATION OF ANTIBIOTIC Major: Chemical Engineering and Technology Name: Junxia LI Signature: Supervisor: Prof. Binghua YAO Signature: Abstract COD is a crucial parameter for water pollution degree and has important significance in wastewater control and quality assessment. At present, CODMn and CODCr are the mainly methods of COD determination, but they have several inherent drawbacks, such as time consuming, serious interference by Cl-. As a new method of COD determination, photoelectrocatalysis has attracted attention because of its convenient, accurate and online control properties. In this thesis, used fluorine-doped tin oxide-coated glass (FTO) as substrate, preparation methods of thin film photoelectrodes by the sol-gel method were studied and established a new photoelectrocatalytic method for COD determination. The photoelectrocatalytic activities of the photoelectrodes were tested by degradation of different antibiotics. The experimental results are as follows: (1) A TiO2 thin film deposited on FTO was prepared by the sol-gel method. With glucose as response substrate, high pressure mercury lamp as light source, influencing factors of COD determination by photoelectrocatalytic method were discussed in three-electrode system. The results showed that Qnet responded linearly to CODth in the range of 10~1000 mg·L-1 with the detection limit of 2 mg·L-1 under the experimental conditions of E=+0.5 V, pH=5~8, c =0.1 NaSO mol·L-1. When the concentration range of Cl- from 0 mg·L-1 to 1500 mg·L-1, the COD value determined was nearly independent of Cl- variations. Real sample analyses were also carried out and the COD value of real samples determined by photoelectrocatalytic method agreed well with the standard method. (2) A ZrO2-TiO2 thin film deposited on FTO was prepared with