化成箔生产含cr（ⅵ）废水综合处理的研究-环境工程专业论文.docxVIP

水溶液的酸碱度，Cr(Ⅵ)离子得以去除。反应后催化剂经酸处理，其活性恢复并可重复使用。 水溶液的酸碱度，Cr(Ⅵ)离子得以去除。反应后催化剂经酸处理， 其活性恢复并可重复使用。 最后，对以TiO：为催化剂，光催化还原cr(Ⅵ)的反应动力学 进行了试验研究，结果表明，悬浮相光催化还原cr(Ⅵ)的反应表 现为一级反应，反应速率遵从多相催化动力学方程 ——Langmuir_Hinshelwood方程。 关键词Cr(VI)废水有机物MK光催化动力学 AbstractTreating Abstract Treating Cr(VI)一containing wastewater is an important task with practical value．On the basis of surveying Cr(VI)一containing wastewater controlling approaches inside and outside country，and takeing a formed—foil factory wastewater as all example， Cr(vI)一containing wastewater treated by organic compoundⅣⅡ( reduction and photo-catalytic deoxidization was studied systemically in this paper． In the study of treating high concentration(1 7000mg／L) Cr(VI)-containing wastewater by organic MK，factors affection reduction reaction were studied in details，such as reductant amount， pH value，time and temperature of reaction，etc．The optimization were determined to be：amount ofMK：109a．；temperature：98℃．pH value：1．0。time of reaction：1 0rain．Atier deposition process．pure Cr(OH)3 Can be reclaimed．The removal rate of Cr(VI)cail reach the standard ofcharging． Aiming at the low concentration cleaning liquor and rudimental Cr(VI)solution，the photocatalytic deduction Was adopted．Factors affecting photocatalytie deduction reaction were studied in a L16(43) orthogonal experiments，such as catalyst amount and varieties，pH value，intensity and time of light irradiation，etc．The affecting factors priority was introduced：catalyst Varieties—÷DH Value---}intensity of light}rradiation—÷time of light irradiation-*catalyst amount． In order to analyze the cause of the affecting factors，adsorption of Cr(VI)on Ti02 decreased with the increase of the suspension pH． The largest Cr(VI、adsorption appeared when its initial concentration was about 1 5mg／L．The existence of H2P04一anion and acetic acid decrease the adsorption efficiency of C“VI)，and formic acid promoted its adsorption efficiency．Other organic molecules had noninterference catalytic reduction of Cr(V