改性聚乙烯火焰喷塑涂层研究-材料学专业论文.docxVIP

摘 摘 要 火焰喷塑是一种环境污染极低的防腐和阻隔涂层制造技术，在航 天航空、汽车、化工等行业有着极其广阔的应用前景。由于目前市场 上大量使用的非极性聚乙烯的火焰喷塑涂层附着力较低，而一些附着 力较高的涂层材料如：乙烯一甲基丙烯酸共聚物(EMAA)等需要进口， 价格昂贵，因此，研究聚乙烯的改性方法和价格低廉的喷塑材料是本 研究的主要目的。另外，研究改性聚乙烯火焰喷塑工艺条件以及喷塑 涂层附着力测量时有效的粘结方法是本研究首先必须完成的任务。 采用掺混改性的方法，向聚乙烯火焰喷塑材料中加入带极性基团 的物质可以增强聚乙烯涂层的极性，加入纳米材料可增强涂层的吸附 能力，这两种方法可提高聚乙烯火焰喷塑涂层的附着力和多方面性能。 本研究主要结论如下： (1)用拉开法测量火焰喷塑涂层附着力时，有效的粘接方法是采用加 热粘结，并在粘结柱头表面预涂EMAA涂层，该方法能保证良好 的测量效果和试验的可重复性。 (2)乙烯一甲基丙烯酸共聚物(EMAA)的加入增强了聚乙烯材料的 极性，在很大程度上提高了PE涂层的附着力，并能提高PE涂层 的力学性能、耐化学腐蚀性能、耐盐雾腐蚀及光老化性能。在PE 中加入25％EMAA能使涂层的附着力提高60％，涂层抗冲击强 度增加58．3％。 (3)加入纳米Ti02、Si02．。能提高聚乙烯火焰喷塑涂层的附着力、抗 冲击性能及涂层的耐老化性能。含纳米Al：03的涂层具有极高的 耐冲刷磨损能力。 (4)在聚乙烯火焰喷塑材料中按重量百分比加入25％EMAA可以制 成一种性能优良价格相对低廉的火焰喷塑材料。 关键词： 火焰喷塑涂层 改性聚乙烯 EMAA 纳米材料 A A STUDY ON MODIFIED POLYETHYLENE COATINGS BY FLAME SPRAYING Abstract Plastic flame spraying is one of the surface engineering techniques that have the slightest pollution of environment．The polymeric coatings are now widely used as the corrosion resistance，barrier coating in the fields Of aircraft，automotive and chemical industry．Currently non·polar Polyethylene(PE)is the most popular materials in the market but the coating can not fit some special needs because its low adhesion．Other materials with high adhesion need to import from foreign countries at very high prices． Developing a modified PE method and a lower cost polymer used in the flame spraying are the objectives of this study．Improving the method of bonding stud with coating surface and studying the process conditions of PE flame spray are important tasks in this work． In this paper the modified PE methods are presented．To improve adhesion and other properties of PE spmy coatings，it is expected that the coatings blending PE with the polar polymer brings polar group into the materials of flame spraying or dispersing the nanosized materials in PE matrix improves the absorbability of coatings。The main results of this study are summarized as follows． I To measure the adhesion of polymer coating to steel substrate by the di