纳米组装和复合结构mgfe2o4负极材料的合成及性能研究-无机化学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 ABSTRACTWith ABSTRACT With the rapid development of new energy industry，as the best of them，Lithium—ion battery also gradually highlights with the advantages of energy density，safety，cost and on．Its electrochemical performance is influenced by many factors，such negative and anode materials，conductive agenm，binder, electrolyte，separator,production processes and on．But anode materials play important role in enhancing the electricity performance the materials．But far，people have MgFe204 have capacity much h igher／、、than carbon and other less research MgFe204 anode material ，in the studied reports ，the synthetic methods complicated and experiment conditions severe．Moreover，it is semiconductor itself,SO its electrical conductivity is poor． As anode material，its rate performance in the high current density is not good．While at the same time，the intercalation／deintercalation of lithium ions volume change，severe pulverization and poor electrical conductivity which result in the unstable cycling performance of MgFe204． The work of this paper is focused employing different methods to prepare structure nano．assembly structure such hollow sphere，solid sphere and core—shell structure，and composite structure(MgFe20dC、MgFe204／CNTs)MgFe204 material．The electrochemical performance is researched． First，this paper chooses the lower melting point and low cost nitrate and citric acid raw material to prepare nano·sized MgFe204．Then it reports facile approach for the synthesis of MgFe204／C using glucose carbon source．And its electrochemical performance is characterized．The composites electrode material delivers capacity of about 1 965 mAh g。1 after 1 00 cycles at 0．1 C．showing excellent cycling performance In order to enhance the capacity retention rate and at the same time try to modify the morphology structure,this paper employs the solvothermal method to synthesize the hollow spherical MgFe204．And the synthesis mechanism is elucidated．The electrochemical performance of