金纳米粒子的二步电解合成及表面增强拉曼散射活性研究Synthesisof.PDF

2007 年第65 卷 化 学 学 报 Vol. 65, 2007 第3 期, 203～206 ACTA CHIMICA SINICA No. 3, 203～206 ·研究论文· 金纳米粒子的二步电解合成及表面增强拉曼散射活性研究 沈理明 姚建林 顾仁敖* (苏州大学化学化工学院 苏州 215123) 摘要 在超声条件下采用二步电解方法在十六烷基三甲基溴化铵/丙酮/水三组分体系中合成金纳米粒子. 首先采用恒 电流或电位的阶跃方法, 使体系中生成较小的金纳米粒子并作为晶种; 接着采用电位双阶跃方法, 使金纳米粒子在原 来基础上继续生长, 控制电解电量可获得不同大小的金纳米粒子. 通过静电作用在洁净的单晶硅片表面组装金纳米粒 子, 获得具有不同形貌的硅片, 并以此作为表面增强拉曼散射基底, 以吡啶为探针分子, 研究了不同基底的表面增强 拉曼散射活性, 结果表明吡啶谱峰强弱与纳米粒子在硅片表面的排列形貌有关. 关键词 电解; 恒电流; 电位阶跃; 静电组装; 表面增强拉曼散射 Synthesis of Gold Nanoparticles by Two Step Electrolysis and Investigation on Their SERS Activities SHEN, Li-Ming YAO, Jian-Lin GU, Ren-Ao* (Department of Chemistry, Suzhou University, Suzhou 215123) Abstract Gold nanoparticles (AuNPs) were synthesized by two step electrolysis in three component sys- tem of cetyltrimethylammonium bromide (CTAB)-acetone-water assisted by ultrasonic irradiation. The con- stant current or potential step technique was applied to the first electrolysis, and small AuNPs were produced as seeds. The double potential step technique was applied to the second electrolysis for the growth of AuNP seeds. The results revealed that the size of the AuNP was dependent on the electrolysis coulomb. A clean Si(111) wafer was immerged into the colloid solution for the assembly of AuNP through the electrostatic in- teraction, and thus the AuNP covered Si(111) surfaces were obtained with different morphology. By using pyridine as probe molecule, the AuNP covered Si(111) surf