熔盐介质中鳞片石墨表面包覆zrc的改性制备及其应用材料科学与工程专业论文.docxVIP

AbstractMolten Abstract Molten salt method is a new powder synthesis method which had the benefits oflowing the reaction temperature，improving the reaction rate and increasing the contact area in system．And zirconium carbide is a superhard material with high chemical stability，good corrosion resistance and high temperature resistance SO that it can be used as a material in surface protection and high temperature structural．Taken advantage of flake graphite’S difficult to dissolve in most molten salt systems and used template method as the growth mechanism，C-ZrC composite with ZrC coating layer was synthesized and the action mechanism ofreaction temperature，reaction time，molten salt composition and graphite size to phase composition and microstructure were studied．In addition，reaction kinetic model was established based on graphite’S stratified structure and the control mechanism of reaction rate was confirmed．In order to confirm the control mechanism of oxidation rate， the diffusion control model ofboundary layer in high-temperature oxidation was established and kinetic parameters were calculated further．At last，the influences of different content of C—ZrC on material’S antioxidation and slag resi stance by bringing C—ZrC composite in AlE03一C refractories were researched． (1)Used molten salt method in argon，ZrC coating layer was successfully synthesized on the surfaces of nature graphite by in—situ reaction in the temperature range of 900℃to 1 200℃and C-ZrC composite structure was formed between ZrC and graphite．In NaCl一 NaF molten salt media，zirconium could achieve effective transport of mass SO that zirconium could react quickly with graphite in molten salt system with template method By rising reaction temperature，it was further generated to the synthesis of ZrC and the growth of grains．Meanwhile，made external diffusion model eligible by studying the thickness of ZrC coating layer in different reaction time (2)Used the method of Kissinger to calculate kinetic par