合肥学院周小龙渗透汽化膜处理低浓度甲醇废水的研究进展.docVIP

渗透汽化膜处理低浓度甲醇废水的研究进展 周小龙，杨艳，谷圣军，刘俊生S邵国泉 (合肥学院膜材料与膜过程重点实验室化学与材料工程系合肥230022) 摘要：由于石油资源短缺和我国新能源战略的进一步实施，甲醇被认为是主要的石油替代品之一。 随着甲醇需求暈的增加，其生产过程屮产生的含醇废水也急剧增加，市此造成低浓度甲醇废水污染也H 趋严重，综合治理这种废水污染刻不容缓。渗透气化膜分离技术被认为是治理低浓度甲醇废水的较好方 法2—。本文简要介绍了渗透汽化膜处理低浓度甲醇废水的研究进展，并对其未来的研究趋势和发展前 景进行了展望。 关键词：渗透汽化；甲醇废水；膜分离 中图分类号：TG028. 8 文献标识码：A Progress in the Removal of Dilute Methanol Solution by Pervaporation Xiaolong Zhou, Yan Yang, Shengjun Gu, Junsheng Liu*, Guoquan Shao (Key Laboratory of Membrane Materials Processes, Department of Chemical and Materials Engineering,Hefei University, 373 Huangs han Road, Hefei, 230022, China) Abstract: With the sharp drop in the resource of mineral fuel and the further implementation of Chinese strategical plan for new energies, many efforts are made to develop new substitutes for petroleum? Among which, methcinol is regarded as one of the most promising and renewable new candidates? However, the pollution from dilute methanol solution increases with an increase in the demand for methanol. Consequently, the removal of methanol from contaminated water is turned into significantly urgent. Currently, various novel approaches are proposed to remove the pollution from methanol. Among them, membrane separation by pervaporation is expected to be one of the most useful and promising methods. This review is to summarize the techniques for the removal of methanol from the contaminated water. The present states and future perspective are also discussed. Keywords: pervaporation; methanol wastewater; membrane separation ’基金项H：安徽省自然科学妹金资助项H (No.090415211). 第一作者简介：周小龙，男，1989生，合肥学院化学与材料工程系2008级学生 通讯作者简介:刘俊生，男，1964生，教授,博士，研究方向：高分子功能膜及膜分离技术,电话：0551-2158437, E-mail: isliu(3)hfuu.edu.c n 1引言 近年來，由于石油资源短缺和我国新能源战略的进一步实施，用于生产无铅汽油添加 剂MTBE（甲基叔丁基储）和用作石油替代品的燃料甲醇需求量每年以10%左右的速度增长。 市场的巨大需求刺激了我国天然气甲醇、煤基甲醇大型牛产装置的相继上马以及甲醇牛产 企业的急剧膨胀卩⑶。由于国家发改委制定的《天然气利用政策》已于2007年8月30 H止 式颁布实施，限制了我国天然气甲醇的生产；造成国内甲醇生产向以煤为原料的领域集中 ⑵。同时，我国在煤气化、煤液化、煤化工联产等领域的研究开发也取得了重大进展，为 醇联燃料、甲醇制烯坯等新兴煤化工产业发展提供了坚强的技术支撑。随着国家有序推进 煤化工领域示范项目的建设