y2sio5和sr2sio4发光材料的制备与性能研究材料科学与工程专业论文.docxVIP

北京化工大学硕士学位论文附近产生发射带，Bi3+的最佳掺杂浓度为1．5m01％。Bi3+，Eu3+共掺杂后导 北京化工大学硕士学位论文 附近产生发射带，Bi3+的最佳掺杂浓度为1．5m01％。Bi3+，Eu3+共掺杂后导 致样品在612nm出现Eu3+的典型发射主峰，对应Eu3+的5Do一7F2跃迁。 通过调控Bi3+但u3十掺杂比，可实现样品从蓝光到红光的转变。 3．对Sr2Si04：Ce3+，Tb3+，Yb3+的发光性能进行了系统研究。Sr2Si04： Yb3+在紫外激发下，由于Yb3+的2F5／2-÷2F7t2跃迁产生峰值位于977nm左 右的近红外发射，与硅带隙宽匹配。通过ce3十和Tb3+的引入，能够显著 增强荧光粉在近红外的发射。机理分析表明，在三掺杂中，Ce3+与Tb3+ 之间通过电偶极对电偶极产生共振能量传递，Tb3+和Yb3+之间通过共合作 能量传递过程，从而实现发光材料下转换。所得样品的最佳配比为： Sr2Si04：4m01％Ce3+，6m01％Tb3+。3m01％Yb3+。 关键词：Y2Si05，Sr2Si04，光致发光，能量传递，下转换 Ⅱ 万方数据 ABSTRACTPREPARATIoN ABSTRACT PREPARATIoN AND PHoTOLUMD呵ESCENCE PROPERTIES oF Y2SiOs AND Sr2Si04 PHOSPHORS ABSTRACT The w．LED is considered as an environmental friendly lighting due to its advantages such as high lighting efficiency,pollution—free and long lifetime． The ideal of white light could be prepared by using the effective combination of phosphors and LED chips，therefore the fluorescent light powder performance is good or bad，which will influence directly on the color effect of white LED．Solar cells can be used in the communications／electricity, petroleum，marine，and many other areas as the pollution—free renewable solar energy because it can convea the solar energy into electrical energy．But the solar cell does not match with the solar spectrum，leading to the low efficiency for the light conversion．Therefore，looking for the right down·conversion luminescence materials is of great significance，in which the ultraviolet(UV) wavelengths unabsorbed by solar cells can be convened into the visible‘near infrared(N瓜)wave band．In this paper,Ce3+_doped and Bi3+-Eu3+CO-doped III 万方数据 万方数据 万方数据 北京化工大学硕士学位论文Y2Si05 北京化工大学硕士学位论文 Y2Si05 phosphors which have potential to be used for LED were synthesized by solid-state reaction method respectively． Ce抖．Tb3+．Yb3+tri．doped Sr2Si04 down．conversion material for Si solar cells were also studied．The thesis consists ofthe following results： 1．The single phase X2．Y2Si05：Ce3+phosphors were prepared by the solid-state method at high temperatures．The e