丁集矿煤中伴生元素分布及其环境意义环境科学专业论文.docxVIP

中田科学技术火学顾一lj学位论义丁集矿煤中伴生元素分布及其环境意义ABSTRACT 中田科学技术火学顾一lj学位论义丁集矿煤中伴生元素分布及其环境意义 ABSTRACT Based on substantial investigations on literatures about regent areas home and m abroad，5 1 elements in 1 1 coal，1 3伽coal，water and soil samples of Dingj i coal mine were tested by ICP—MS，ICP—OES and AFS．It was first time to test SO many elements in coal samples in one experiment．Combine with the knowledge of coal geochemistry, environmental geochemistry and statistics，the geochemical characters of companying elements in coal were discussed detailedly．With Nemerow Index model，index of geoaccurnulation and potential ecological risk index methods，the surface environment of Dingji coal mine was evaluated．The results indicate as follows． (1)The results show a prominent enrichment of elements As，Se，Mo，Sb，W：Bi， Cd，Ni，B，Hg，Cu，Li in Dingji coal mine，while deficit of elements PBa，Mn，Be，Ho， Dy’Sm，Y Gd，Eu，La，Sr,Fe，Si，Mg，Ca，Na，K．The 13m coal shows a higher content of most elements than the 1 1幽coal．Affected by the top and bottom layers， there is variations for some elements in the vertical direction，and this variation is fluctuated with the deposition environments of parallel layers of coal，making it an indicator for correlation of coal seams．(2)Sr／Ba analysis implies a terrestrial deposition of the core，however,corfelmion，cluster and main factor analysis all show traces of marine deposition at both 1 1‘h and 13幽coals．(3)Rare earth elements are averagely less in Dingji coal mine than Huaibei coalfield and C—P coals of Huabei； Comparing with the mean value of China，there is a deficit of light rare earth elements and all enrichment ofheaw rare earth elements．And Dingii mine generally has higher rare earth elements content than the global mean，all obvious enrichment is shown． Meanwhile，1 3‘“coal shows a higher contents for most rate earth elements than 1 1出 COal．First direct evidence shows the total rare earth content in coalis much more than that in the top and bottom layers，and rare earth ele