改性水性丙烯酸树脂的制备及其性能研究有机化学专业论文.docxVIP

和漆膜性能的影响。结果表明：当引发剂用量为3％，环氧树脂前期加入且 和漆膜性能的影响。结果表明：当引发剂用量为3％，环氧树脂前期加入且 环氧树脂用量4％，有机硅用量3％时，合成树脂的水分散体乳液呈乳白色 泛蓝光，具有良好的储存稳定性，涂膜的附着力0级、硬度2H，耐水性及 耐热性等性能良好。 关键词：水性丙烯酸树脂，叔碳酸缩水甘油酯，有机硅氧烷，化学改性， 双组分清漆 HI 万方数据 Study Study on Preparation and Properties of modified Water-borne acrylic resin synthesis ABSTRACT In recent years，the water-soluble coating is a new class of saving resources， low manufacturing cost,the characteristics of green environmental protection， and SO developed rapidly．The application and development of water-borne coatings decrease the pollution of organic solvent to the environment and the harm to human body．Acrylic resin is very widely used in synthetic resin．It has excellent durability,luster,light color,hardness and flexibility,and occupies an important position in the field of coating．but in the practical application of water soluble coatings also has some defects，such as low solid content， viscosity,film resistance to water shortage，etc．，which makes its widely application is restricted．This paper aimed at the problems of water-based acrylic resin coating did some modification，specific work is as follows： (1)111e water-bome hydroxyl acrylic resin was prepared and applied to two component acrylic—polyurethane coating，by free radical solution polymerization method and semi—continuous adding using methyl meth—acrylate， styrene，butyl acrylate，acrylic acid，ethyl acrylate and glycidyl Versatate as raw materials．The effects of species and amount of initiator,ratio of hard／soft monomers，amount of acrylic acid，amount of E·l 0p，dropping method， reaction temperature，degree of neutralization on the properties of resin were investigated．砀e structure of the resin was characterized by Fourier infrared spectromete．Thermal stability of the resin was investigated by thermogravimetric analyzer．The change of two—component coating viscosity and film hardness over time were studied．The results showed that when the dosage of initiator was 2％，ratio hard／soft monomers 45／20，acrylic a