超支化线性聚合物的合成及其对皮革的加脂效能研究化学工程与技术专业论文.docxVIP

的摩尔比为1：1．4。通过红外光谱的分析，证明了产物的成功合成。随后利 的摩尔比为1：1．4。通过红外光谱的分析，证明了产物的成功合成。随后利 用正交实验确定了该端羧基产品的最佳加脂条件：Nil温度50℃，加脂时 间40min，产品用量为蓝湿革质量的8％。该类产品的加脂规律性与端羟基 产品类似，均表现为随产物代数的增高，成革柔软度降低，增厚率降低，部 位差减小。 线性结构的多寡是另一个影响皮革柔软度的重要因素，本论文采用阴 离子开环聚合法，以丙三醇和环氧丙醇为原料，甲醇钠为催化剂，制备得到 了第三代超支化聚醚，然后利用油酸对其进行不同程度的酯化改性，得到了 端羟基超支化．线性聚醚(HBPG-X系列1，利用FT．IR以及1H-NMR证明了 反应的成功进行。随后将其应用于蓝湿革的加脂，粒度测定结果显示产物的 分子体积随线性长链的增多而增大，受分子尺寸的影响，线性链段的增多并 没有提高成革的柔韧性。另外，相比于聚酯产品，聚醚产品的加脂效果更为 优越。 关键词：超支化聚合物，烷醇酰胺，两亲性化合物，皮革，加脂性能 万方数据 Study Study on the Synthesis of Hyperbranched·-linear Polymer And Its Effect Oil Leather as FatHquor ABSTRACT Hydroxyl terminated hyperbranched-linear polyesters of generations l～3 (CHAPx category)which can be used as fatliquor were synthesized by one-pot method using coconut-oil fatty acid diethanolamide(CDEA)as a core， dimethylol propionic acid(DMPA．)as monomers and p-toluenesulfonic acid (p—TSA)as catalyst．Next,carboxyl terminated hyperbranched-linear polyesters of generations 1--3(MHaPx category)which Can also be used as fatliquor were synthesized by grafting maleic anhydride．Hydroxyl terminated hyperbranched- linear polyethers(HBPG-X category)Were synthesized using glycerol， epoxypropane and oleic acid as materials at the same time．Then，the structures and emulsion characteristics of CI-IBP。category,MHBPx category and HBPG-X category were studied．Finally,their effects on retanned or tanned leather as fatliquor were analyzed by measuring softness and mechanical properties of fatliquored leather． The appropriate reaction conditions were optimized by both single factor experiments and orthogonal experiments．The results are as follows：The reaction temperature is 1 60C，the reaction time is 4h and the quantity of catalyst is equal to 1％of feedstock CDEA．The molecular structures of the products were confirmed by FT-IR,1H NMR．Surface activities were measured bY surface tension meter．It was shown that CHBPx category performs good surface activities and their surface tensions decrease with the generations．In addi