二茂铁基杯4芳烃衍生物的合成与性能研究有机化学专业论文.docxVIP

摘要Abstract 摘要 Abstract l Regarded鹪‘the third supramolecular receptor’along谢Ⅱl clown ethers and ； cyclodetrins，calixarenes are a class of well defined macrocyclic oligomers of phenols bridged by methylene groups．Owing toⅡleir unique three-dimensional cavities， convenient preparation in large quantities，versatile complexation and recognization abilities towards iOILS or molecules，nley have received considerable attentions in recent years．Due to easy modification on both lower and upper rims，the parent calixarenes ficquently serve as molecular scaffolds for the construction of morc elaborate supramolecular systems．The supramolecular electrochemical recognition based on redox—active receptors is a new emerging topical area of supramolecular chemistry．It is greatly important to both field of supramolecular chemistry and practical domain of advanced techniques such as ion transport， molecular switches， electrochemical molecular devices，and chemical SC=疆qSOrs．Therefore，an investigation on design, synthesis and supramolecular properties of calix[4]arene multisite receptors containing ferrocenes as redox-active probes Was systematically carried out．The main results ale as follows： 叠．．J 1．The recent research progess of calixarene based redox—active receptors，including molecular design，chemical synthesis and meir electrochemical recognition and sensing properties，was briefly reviewed． 2．Organic·inorganic hybrid supramolecular complex Was designed and synthesized．R Was proved that complexes containing Cu in electron pairs，no single d∞tromc structure，indicating the presence of Cu complexes in the form of Cu(13I． 3．Two new type of ferrocene—based calix[4]arene receptors we心designed and synthesized，which ferrocene Was electrochemical active center．Cyclic VoltammetD， and UV spectra showed that these compounds have a good effective of electrochemical response to the series of cations and anions，as well as the recognition and sensing properties of the compounds to the series of ammo